First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula

Autores
Jang, Eunho; Park, Ki-Tae; Yoon, Young Jun; Kim, Kitae; Gim, Yeontae; Chung, Hyun Young; Lee, Kitack; Choi, Jinhee; Park, Jiyeon; Park, Sang-Jong; Koo, Ja-Ho; Fernandez, Rafael Pedro; Saiz López, Alfonso
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Dimethyl sulfide (DMS) produced by marine algae represents the largest natural emission of sulfur to the atmosphere. The oxidation of DMS is a key process affecting new particle formation that contributes to the radiative forcing of the Earth. In this study, atmospheric DMS and its major oxidation products (methanesulfonic acid, MSA; non-sea-salt sulfate, nss-SO42?) and particle size distributions were measured at King Sejong station located in the Antarctic Peninsula during the austral spring?summer period in 2018?2020. The observatory was surrounded by open ocean and first-year and multi-year sea ice. Importantly, oceanic emissions and atmospheric oxidation of DMS showed distinct differences depending on source regions. A high mixing ratio of atmospheric DMS was observed when air masses were influenced by the open ocean and first-year sea ice due to the abundance of DMS producers such as pelagic phaeocystis and ice algae. However, the concentrations of MSA and nss-SO42? were distinctively increased for air masses originating from first-year sea ice as compared to those originating from the open ocean and multi-year sea ice, suggesting additional influences from the source regions of atmospheric oxidants. Heterogeneous chemical processes that actively occur over first-year sea ice tend to accelerate the release of bromine monoxide (BrO), which is the most efficient DMS oxidant in Antarctica. Model-estimates for surface BrO confirmed that high BrO mixing ratios were closely associated with first-year sea ice, thus enhancing DMS oxidation. Consequently, the concentration of newly formed particles originated from first-year sea ice, which was a strong source area for both DMS and BrO was greater than from open ocean (high DMS but low BrO). These results indicate that first-year sea ice plays an important yet overlooked role in DMS-induced new particle formation in polar environments, where warming-induced sea ice changes are pronounced.
Fil: Jang, Eunho. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Park, Ki-Tae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Yoon, Young Jun. Korea Polar Research Institute; Corea del Sur
Fil: Kim, Kitae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Gim, Yeontae. Korea Polar Research Institute; Corea del Sur
Fil: Chung, Hyun Young. University of Science and Technology; Corea del Sur. Korea Polar Research Institute; Corea del Sur
Fil: Lee, Kitack. Pohang University of Science and Technology; Corea del Sur
Fil: Choi, Jinhee. Korea Polar Research Institute; Corea del Sur
Fil: Park, Jiyeon. Korea Polar Research Institute; Corea del Sur
Fil: Park, Sang-Jong. Korea Polar Research Institute; Corea del Sur
Fil: Koo, Ja-Ho. Yonsei University; Corea del Sur
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; España
Materia
DMS
New Particle Formation
Bromine Chemistry
Antarctic Peninsula
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/233057
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/233057
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic PeninsulaJang, EunhoPark, Ki-TaeYoon, Young JunKim, KitaeGim, YeontaeChung, Hyun YoungLee, KitackChoi, JinheePark, JiyeonPark, Sang-JongKoo, Ja-HoFernandez, Rafael PedroSaiz López, AlfonsoDMSNew Particle FormationBromine ChemistryAntarctic Peninsulahttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Dimethyl sulfide (DMS) produced by marine algae represents the largest natural emission of sulfur to the atmosphere. The oxidation of DMS is a key process affecting new particle formation that contributes to the radiative forcing of the Earth. In this study, atmospheric DMS and its major oxidation products (methanesulfonic acid, MSA; non-sea-salt sulfate, nss-SO42?) and particle size distributions were measured at King Sejong station located in the Antarctic Peninsula during the austral spring?summer period in 2018?2020. The observatory was surrounded by open ocean and first-year and multi-year sea ice. Importantly, oceanic emissions and atmospheric oxidation of DMS showed distinct differences depending on source regions. A high mixing ratio of atmospheric DMS was observed when air masses were influenced by the open ocean and first-year sea ice due to the abundance of DMS producers such as pelagic phaeocystis and ice algae. However, the concentrations of MSA and nss-SO42? were distinctively increased for air masses originating from first-year sea ice as compared to those originating from the open ocean and multi-year sea ice, suggesting additional influences from the source regions of atmospheric oxidants. Heterogeneous chemical processes that actively occur over first-year sea ice tend to accelerate the release of bromine monoxide (BrO), which is the most efficient DMS oxidant in Antarctica. Model-estimates for surface BrO confirmed that high BrO mixing ratios were closely associated with first-year sea ice, thus enhancing DMS oxidation. Consequently, the concentration of newly formed particles originated from first-year sea ice, which was a strong source area for both DMS and BrO was greater than from open ocean (high DMS but low BrO). These results indicate that first-year sea ice plays an important yet overlooked role in DMS-induced new particle formation in polar environments, where warming-induced sea ice changes are pronounced.Fil: Jang, Eunho. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del SurFil: Park, Ki-Tae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del SurFil: Yoon, Young Jun. Korea Polar Research Institute; Corea del SurFil: Kim, Kitae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del SurFil: Gim, Yeontae. Korea Polar Research Institute; Corea del SurFil: Chung, Hyun Young. University of Science and Technology; Corea del Sur. Korea Polar Research Institute; Corea del SurFil: Lee, Kitack. Pohang University of Science and Technology; Corea del SurFil: Choi, Jinhee. Korea Polar Research Institute; Corea del SurFil: Park, Jiyeon. Korea Polar Research Institute; Corea del SurFil: Park, Sang-Jong. Korea Polar Research Institute; Corea del SurFil: Koo, Ja-Ho. Yonsei University; Corea del SurFil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaElsevier2022-01-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/233057Jang, Eunho; Park, Ki-Tae; Yoon, Young Jun; Kim, Kitae; Gim, Yeontae; et al.; First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula; Elsevier; Science of the Total Environment; 803; 10-1-2022; 1-90048-96971879-1026CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0048969721050774info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2021.150002info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-08-25T15:43:15Zoai:ri.conicet.gov.ar:11336/233057instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-08-25 15:43:15.616CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
title First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
spellingShingle First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
Jang, Eunho
DMS
New Particle Formation
Bromine Chemistry
Antarctic Peninsula
title_short First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
title_full First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
title_fullStr First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
title_full_unstemmed First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
title_sort First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula
dc.creator.none.fl_str_mv Jang, Eunho
Park, Ki-Tae
Yoon, Young Jun
Kim, Kitae
Gim, Yeontae
Chung, Hyun Young
Lee, Kitack
Choi, Jinhee
Park, Jiyeon
Park, Sang-Jong
Koo, Ja-Ho
Fernandez, Rafael Pedro
Saiz López, Alfonso
author Jang, Eunho
author_facet Jang, Eunho
Park, Ki-Tae
Yoon, Young Jun
Kim, Kitae
Gim, Yeontae
Chung, Hyun Young
Lee, Kitack
Choi, Jinhee
Park, Jiyeon
Park, Sang-Jong
Koo, Ja-Ho
Fernandez, Rafael Pedro
Saiz López, Alfonso
author_role author
author2 Park, Ki-Tae
Yoon, Young Jun
Kim, Kitae
Gim, Yeontae
Chung, Hyun Young
Lee, Kitack
Choi, Jinhee
Park, Jiyeon
Park, Sang-Jong
Koo, Ja-Ho
Fernandez, Rafael Pedro
Saiz López, Alfonso
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv DMS
New Particle Formation
Bromine Chemistry
Antarctic Peninsula
topic DMS
New Particle Formation
Bromine Chemistry
Antarctic Peninsula
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Dimethyl sulfide (DMS) produced by marine algae represents the largest natural emission of sulfur to the atmosphere. The oxidation of DMS is a key process affecting new particle formation that contributes to the radiative forcing of the Earth. In this study, atmospheric DMS and its major oxidation products (methanesulfonic acid, MSA; non-sea-salt sulfate, nss-SO42?) and particle size distributions were measured at King Sejong station located in the Antarctic Peninsula during the austral spring?summer period in 2018?2020. The observatory was surrounded by open ocean and first-year and multi-year sea ice. Importantly, oceanic emissions and atmospheric oxidation of DMS showed distinct differences depending on source regions. A high mixing ratio of atmospheric DMS was observed when air masses were influenced by the open ocean and first-year sea ice due to the abundance of DMS producers such as pelagic phaeocystis and ice algae. However, the concentrations of MSA and nss-SO42? were distinctively increased for air masses originating from first-year sea ice as compared to those originating from the open ocean and multi-year sea ice, suggesting additional influences from the source regions of atmospheric oxidants. Heterogeneous chemical processes that actively occur over first-year sea ice tend to accelerate the release of bromine monoxide (BrO), which is the most efficient DMS oxidant in Antarctica. Model-estimates for surface BrO confirmed that high BrO mixing ratios were closely associated with first-year sea ice, thus enhancing DMS oxidation. Consequently, the concentration of newly formed particles originated from first-year sea ice, which was a strong source area for both DMS and BrO was greater than from open ocean (high DMS but low BrO). These results indicate that first-year sea ice plays an important yet overlooked role in DMS-induced new particle formation in polar environments, where warming-induced sea ice changes are pronounced.
Fil: Jang, Eunho. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Park, Ki-Tae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Yoon, Young Jun. Korea Polar Research Institute; Corea del Sur
Fil: Kim, Kitae. Korea Polar Research Institute; Corea del Sur. University of Science and Technology; Corea del Sur
Fil: Gim, Yeontae. Korea Polar Research Institute; Corea del Sur
Fil: Chung, Hyun Young. University of Science and Technology; Corea del Sur. Korea Polar Research Institute; Corea del Sur
Fil: Lee, Kitack. Pohang University of Science and Technology; Corea del Sur
Fil: Choi, Jinhee. Korea Polar Research Institute; Corea del Sur
Fil: Park, Jiyeon. Korea Polar Research Institute; Corea del Sur
Fil: Park, Sang-Jong. Korea Polar Research Institute; Corea del Sur
Fil: Koo, Ja-Ho. Yonsei University; Corea del Sur
Fil: Fernandez, Rafael Pedro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Saiz López, Alfonso. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; España
description Dimethyl sulfide (DMS) produced by marine algae represents the largest natural emission of sulfur to the atmosphere. The oxidation of DMS is a key process affecting new particle formation that contributes to the radiative forcing of the Earth. In this study, atmospheric DMS and its major oxidation products (methanesulfonic acid, MSA; non-sea-salt sulfate, nss-SO42?) and particle size distributions were measured at King Sejong station located in the Antarctic Peninsula during the austral spring?summer period in 2018?2020. The observatory was surrounded by open ocean and first-year and multi-year sea ice. Importantly, oceanic emissions and atmospheric oxidation of DMS showed distinct differences depending on source regions. A high mixing ratio of atmospheric DMS was observed when air masses were influenced by the open ocean and first-year sea ice due to the abundance of DMS producers such as pelagic phaeocystis and ice algae. However, the concentrations of MSA and nss-SO42? were distinctively increased for air masses originating from first-year sea ice as compared to those originating from the open ocean and multi-year sea ice, suggesting additional influences from the source regions of atmospheric oxidants. Heterogeneous chemical processes that actively occur over first-year sea ice tend to accelerate the release of bromine monoxide (BrO), which is the most efficient DMS oxidant in Antarctica. Model-estimates for surface BrO confirmed that high BrO mixing ratios were closely associated with first-year sea ice, thus enhancing DMS oxidation. Consequently, the concentration of newly formed particles originated from first-year sea ice, which was a strong source area for both DMS and BrO was greater than from open ocean (high DMS but low BrO). These results indicate that first-year sea ice plays an important yet overlooked role in DMS-induced new particle formation in polar environments, where warming-induced sea ice changes are pronounced.
publishDate 2022
dc.date.none.fl_str_mv 2022-01-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/233057
Jang, Eunho; Park, Ki-Tae; Yoon, Young Jun; Kim, Kitae; Gim, Yeontae; et al.; First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula; Elsevier; Science of the Total Environment; 803; 10-1-2022; 1-9
0048-9697
1879-1026
CONICET Digital
CONICET
url http://hdl.handle.net/11336/233057
identifier_str_mv Jang, Eunho; Park, Ki-Tae; Yoon, Young Jun; Kim, Kitae; Gim, Yeontae; et al.; First-year sea ice leads to an increase in dimethyl sulfide-induced particle formation in the Antarctic Peninsula; Elsevier; Science of the Total Environment; 803; 10-1-2022; 1-9
0048-9697
1879-1026
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0048969721050774
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2021.150002
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.265058

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