Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates

Autores
Villafranca, Juan C.; Rosales, Gustavo Daniel; Esquivel, Marcelo Ricardo Oscar; Rodriguez, Mario Humberto; Altieri, Tamara Antonella; Arancibia, Nicolás; Martinis, Estefanía Mabel
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The contamination of water resources by heavy metals, particularly arsenic, represents a critical environmental and public health challenge globally. Arsenic, originating from both geogenic processes and anthropogenic activities such as mining and industrial discharges, accumulates in aquatic systems, posing severe risks due to its toxicity. This study investigates the adsorption efficacy of synthetic aluminosilicates, specifically albite and nepheline, synthesized as by-products from an innovative lithium extraction process, for the remediation of arsenic-contaminated water. A comprehensive suite of characterization techniques, including XRD, SEM-EDS, FTIR, zeta potential, BET, adsorption kinetics, and isotherms, was employed to thoroughly evaluate the adsorbent materials. The research delineates the influence of solution pH and adsorbent dosage on the arsenic adsorption capacity of these materials. Comprehensive analyses of adsorption mechanisms and adsorbate–adsorbent interactions were conducted to elucidate the underlying processes. The results of this study demonstrate the potential of these synthetic aluminosilicates as efficient, low-cost adsorbents for arsenic removal, offering a viable and sustainable approach to address arsenic pollution in water resources. The innovative aspect of utilizing by-products from lithium extraction not only provides a novel solution for arsenic remediation but also adds value to industrial waste, promoting a circular economy. The findings have significant implications for the development of scalable and eco-friendly water treatment technologies, addressing both environmental sustainability and public health concerns.
Fil: Villafranca, Juan C.. Universidad Nacional de Cuyo. Facultad de Ingeniería; Argentina
Fil: Rosales, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Esquivel, Marcelo Ricardo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina. Universidad Nacional del Comahue; Argentina
Fil: Rodriguez, Mario Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Altieri, Tamara Antonella. Comisión Nacional de Energía Atómica; Argentina
Fil: Arancibia, Nicolás. Universidad de Santiago de Chile; Chile
Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ingeniería; Argentina
Materia
LITHIUM
ARSENIC
ALUMINOSILICATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/291414
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicatesVillafranca, Juan C.Rosales, Gustavo DanielEsquivel, Marcelo Ricardo OscarRodriguez, Mario HumbertoAltieri, Tamara AntonellaArancibia, NicolásMartinis, Estefanía MabelLITHIUMARSENICALUMINOSILICATEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The contamination of water resources by heavy metals, particularly arsenic, represents a critical environmental and public health challenge globally. Arsenic, originating from both geogenic processes and anthropogenic activities such as mining and industrial discharges, accumulates in aquatic systems, posing severe risks due to its toxicity. This study investigates the adsorption efficacy of synthetic aluminosilicates, specifically albite and nepheline, synthesized as by-products from an innovative lithium extraction process, for the remediation of arsenic-contaminated water. A comprehensive suite of characterization techniques, including XRD, SEM-EDS, FTIR, zeta potential, BET, adsorption kinetics, and isotherms, was employed to thoroughly evaluate the adsorbent materials. The research delineates the influence of solution pH and adsorbent dosage on the arsenic adsorption capacity of these materials. Comprehensive analyses of adsorption mechanisms and adsorbate–adsorbent interactions were conducted to elucidate the underlying processes. The results of this study demonstrate the potential of these synthetic aluminosilicates as efficient, low-cost adsorbents for arsenic removal, offering a viable and sustainable approach to address arsenic pollution in water resources. The innovative aspect of utilizing by-products from lithium extraction not only provides a novel solution for arsenic remediation but also adds value to industrial waste, promoting a circular economy. The findings have significant implications for the development of scalable and eco-friendly water treatment technologies, addressing both environmental sustainability and public health concerns.Fil: Villafranca, Juan C.. Universidad Nacional de Cuyo. Facultad de Ingeniería; ArgentinaFil: Rosales, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Esquivel, Marcelo Ricardo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina. Universidad Nacional del Comahue; ArgentinaFil: Rodriguez, Mario Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Altieri, Tamara Antonella. Comisión Nacional de Energía Atómica; ArgentinaFil: Arancibia, Nicolás. Universidad de Santiago de Chile; ChileFil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ingeniería; ArgentinaRoyal Society of Chemistry2025-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/291414Villafranca, Juan C.; Rosales, Gustavo Daniel; Esquivel, Marcelo Ricardo Oscar; Rodriguez, Mario Humberto; Altieri, Tamara Antonella; et al.; Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates; Royal Society of Chemistry; RSC Advances; 15; 47; 9-2025; 39461-394762046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/ra/article/15/47/39461/908096/Valorization-of-lithium-extraction-by-productsinfo:eu-repo/semantics/altIdentifier/doi/10.1039/D5RA05708Finfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-08-25T14:38:54Zoai:ri.conicet.gov.ar:11336/291414instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-08-25 14:38:54.559CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
title Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
spellingShingle Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
Villafranca, Juan C.
LITHIUM
ARSENIC
ALUMINOSILICATE
title_short Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
title_full Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
title_fullStr Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
title_full_unstemmed Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
title_sort Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates
dc.creator.none.fl_str_mv Villafranca, Juan C.
Rosales, Gustavo Daniel
Esquivel, Marcelo Ricardo Oscar
Rodriguez, Mario Humberto
Altieri, Tamara Antonella
Arancibia, Nicolás
Martinis, Estefanía Mabel
author Villafranca, Juan C.
author_facet Villafranca, Juan C.
Rosales, Gustavo Daniel
Esquivel, Marcelo Ricardo Oscar
Rodriguez, Mario Humberto
Altieri, Tamara Antonella
Arancibia, Nicolás
Martinis, Estefanía Mabel
author_role author
author2 Rosales, Gustavo Daniel
Esquivel, Marcelo Ricardo Oscar
Rodriguez, Mario Humberto
Altieri, Tamara Antonella
Arancibia, Nicolás
Martinis, Estefanía Mabel
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv LITHIUM
ARSENIC
ALUMINOSILICATE
topic LITHIUM
ARSENIC
ALUMINOSILICATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The contamination of water resources by heavy metals, particularly arsenic, represents a critical environmental and public health challenge globally. Arsenic, originating from both geogenic processes and anthropogenic activities such as mining and industrial discharges, accumulates in aquatic systems, posing severe risks due to its toxicity. This study investigates the adsorption efficacy of synthetic aluminosilicates, specifically albite and nepheline, synthesized as by-products from an innovative lithium extraction process, for the remediation of arsenic-contaminated water. A comprehensive suite of characterization techniques, including XRD, SEM-EDS, FTIR, zeta potential, BET, adsorption kinetics, and isotherms, was employed to thoroughly evaluate the adsorbent materials. The research delineates the influence of solution pH and adsorbent dosage on the arsenic adsorption capacity of these materials. Comprehensive analyses of adsorption mechanisms and adsorbate–adsorbent interactions were conducted to elucidate the underlying processes. The results of this study demonstrate the potential of these synthetic aluminosilicates as efficient, low-cost adsorbents for arsenic removal, offering a viable and sustainable approach to address arsenic pollution in water resources. The innovative aspect of utilizing by-products from lithium extraction not only provides a novel solution for arsenic remediation but also adds value to industrial waste, promoting a circular economy. The findings have significant implications for the development of scalable and eco-friendly water treatment technologies, addressing both environmental sustainability and public health concerns.
Fil: Villafranca, Juan C.. Universidad Nacional de Cuyo. Facultad de Ingeniería; Argentina
Fil: Rosales, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Esquivel, Marcelo Ricardo Oscar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche | Comisión Nacional de Energía Atómica. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología. Unidad Ejecutora Instituto de Nanociencia y Nanotecnología - Nodo Bariloche; Argentina. Universidad Nacional del Comahue; Argentina
Fil: Rodriguez, Mario Humberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Altieri, Tamara Antonella. Comisión Nacional de Energía Atómica; Argentina
Fil: Arancibia, Nicolás. Universidad de Santiago de Chile; Chile
Fil: Martinis, Estefanía Mabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Interdisciplinario de Ciencias Básicas. - Universidad Nacional de Cuyo. Instituto Interdisciplinario de Ciencias Básicas; Argentina. Universidad Nacional de Cuyo. Facultad de Ingeniería; Argentina
description The contamination of water resources by heavy metals, particularly arsenic, represents a critical environmental and public health challenge globally. Arsenic, originating from both geogenic processes and anthropogenic activities such as mining and industrial discharges, accumulates in aquatic systems, posing severe risks due to its toxicity. This study investigates the adsorption efficacy of synthetic aluminosilicates, specifically albite and nepheline, synthesized as by-products from an innovative lithium extraction process, for the remediation of arsenic-contaminated water. A comprehensive suite of characterization techniques, including XRD, SEM-EDS, FTIR, zeta potential, BET, adsorption kinetics, and isotherms, was employed to thoroughly evaluate the adsorbent materials. The research delineates the influence of solution pH and adsorbent dosage on the arsenic adsorption capacity of these materials. Comprehensive analyses of adsorption mechanisms and adsorbate–adsorbent interactions were conducted to elucidate the underlying processes. The results of this study demonstrate the potential of these synthetic aluminosilicates as efficient, low-cost adsorbents for arsenic removal, offering a viable and sustainable approach to address arsenic pollution in water resources. The innovative aspect of utilizing by-products from lithium extraction not only provides a novel solution for arsenic remediation but also adds value to industrial waste, promoting a circular economy. The findings have significant implications for the development of scalable and eco-friendly water treatment technologies, addressing both environmental sustainability and public health concerns.
publishDate 2025
dc.date.none.fl_str_mv 2025-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/291414
Villafranca, Juan C.; Rosales, Gustavo Daniel; Esquivel, Marcelo Ricardo Oscar; Rodriguez, Mario Humberto; Altieri, Tamara Antonella; et al.; Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates; Royal Society of Chemistry; RSC Advances; 15; 47; 9-2025; 39461-39476
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/291414
identifier_str_mv Villafranca, Juan C.; Rosales, Gustavo Daniel; Esquivel, Marcelo Ricardo Oscar; Rodriguez, Mario Humberto; Altieri, Tamara Antonella; et al.; Valorization of lithium extraction by-products: efficient arsenic adsorption using synthetic aluminosilicates; Royal Society of Chemistry; RSC Advances; 15; 47; 9-2025; 39461-39476
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/ra/article/15/47/39461/908096/Valorization-of-lithium-extraction-by-products
info:eu-repo/semantics/altIdentifier/doi/10.1039/D5RA05708F
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.24418

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