Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth

Autores
Legarto, Maria Celeste; Iborra, Agustín; Romero, Juan J.; Padró, Juan M.; Villa Pérez, Cristian; Rafti, Matias; Vega, Isabel Natalia; Giussi, Juan Martín
Año de publicación
2026
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we report copolymers based on zinc dimethacrylate (ZnDMA) and poly(ethylene glycol)methyl ether methacrylate (PEGMA) as versatile platforms for the in situ growth of ZIF-8 polyMOFs.ZnDMA is a suitable monomer which can potentially optimize polyMOF growth, enabling improvedcontrol over the nucleation process and both final structure and morphology. The copolymers were synthesized both as bulk materials from precursor solutions and via surface-initiated Atom Transfer Radical Polymerization (ATRP). The composition and microstructure were investigated using the Fineman-Ross method, complemented by characterization through X-ray photoelectron spectroscopy (XPS), proton nuclear magnetic resonance (1H NMR), thermogravimetric analysis (TGA), aqueous size exclusion chromatography (SEC) and scanning electron microscopy (SEM). We found that variations in structural stability, composition and microstructure of the resulting poly(ZnDMA-co-PEGMA)@ZIF-8 materials can be traced back to conditions affecting polyMOF growth, mainly regarding efficient nucleation and controlled crystalline growth. Overall, these results demonstrate that the hereby proposed synthetic approach to polyMOFs can be employed for the rational design of functional nanostructured porous materials.
Fil: Legarto, Maria Celeste. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Iborra, Agustín. YPF - Tecnología; Argentina
Fil: Romero, Juan J.. YPF - Tecnología; Argentina
Fil: Padró, Juan M.. YPF - Tecnología; Argentina
Fil: Villa Pérez, Cristian. YPF - Tecnología; Argentina
Fil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Vega, Isabel Natalia. YPF - Tecnología; Argentina
Fil: Giussi, Juan Martín. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
PolyMOFs
Tailored Copolymer Microstructure
Surface-Initiated ATRP
ZIF-8 Growth
Polymeric Template
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/291779
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/291779
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growthLegarto, Maria CelesteIborra, AgustínRomero, Juan J.Padró, Juan M.Villa Pérez, CristianRafti, MatiasVega, Isabel NataliaGiussi, Juan MartínPolyMOFsTailored Copolymer MicrostructureSurface-Initiated ATRPZIF-8 GrowthPolymeric Templatehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1In this work, we report copolymers based on zinc dimethacrylate (ZnDMA) and poly(ethylene glycol)methyl ether methacrylate (PEGMA) as versatile platforms for the in situ growth of ZIF-8 polyMOFs.ZnDMA is a suitable monomer which can potentially optimize polyMOF growth, enabling improvedcontrol over the nucleation process and both final structure and morphology. The copolymers were synthesized both as bulk materials from precursor solutions and via surface-initiated Atom Transfer Radical Polymerization (ATRP). The composition and microstructure were investigated using the Fineman-Ross method, complemented by characterization through X-ray photoelectron spectroscopy (XPS), proton nuclear magnetic resonance (1H NMR), thermogravimetric analysis (TGA), aqueous size exclusion chromatography (SEC) and scanning electron microscopy (SEM). We found that variations in structural stability, composition and microstructure of the resulting poly(ZnDMA-co-PEGMA)@ZIF-8 materials can be traced back to conditions affecting polyMOF growth, mainly regarding efficient nucleation and controlled crystalline growth. Overall, these results demonstrate that the hereby proposed synthetic approach to polyMOFs can be employed for the rational design of functional nanostructured porous materials.Fil: Legarto, Maria Celeste. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Iborra, Agustín. YPF - Tecnología; ArgentinaFil: Romero, Juan J.. YPF - Tecnología; ArgentinaFil: Padró, Juan M.. YPF - Tecnología; ArgentinaFil: Villa Pérez, Cristian. YPF - Tecnología; ArgentinaFil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Vega, Isabel Natalia. YPF - Tecnología; ArgentinaFil: Giussi, Juan Martín. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaRoyal Society of Chemistry2026-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/291779Legarto, Maria Celeste; Iborra, Agustín; Romero, Juan J.; Padró, Juan M.; Villa Pérez, Cristian; et al.; Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth; Royal Society of Chemistry; RSC Applied Polymers; 4; 3; 4-2026; 952-9632755-371XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D6LP00021Einfo:eu-repo/semantics/altIdentifier/doi/10.1039/D6LP00021Einfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-08-25T14:54:24Zoai:ri.conicet.gov.ar:11336/291779instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-08-25 14:54:24.587CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
title Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
spellingShingle Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
Legarto, Maria Celeste
PolyMOFs
Tailored Copolymer Microstructure
Surface-Initiated ATRP
ZIF-8 Growth
Polymeric Template
title_short Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
title_full Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
title_fullStr Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
title_full_unstemmed Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
title_sort Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth
dc.creator.none.fl_str_mv Legarto, Maria Celeste
Iborra, Agustín
Romero, Juan J.
Padró, Juan M.
Villa Pérez, Cristian
Rafti, Matias
Vega, Isabel Natalia
Giussi, Juan Martín
author Legarto, Maria Celeste
author_facet Legarto, Maria Celeste
Iborra, Agustín
Romero, Juan J.
Padró, Juan M.
Villa Pérez, Cristian
Rafti, Matias
Vega, Isabel Natalia
Giussi, Juan Martín
author_role author
author2 Iborra, Agustín
Romero, Juan J.
Padró, Juan M.
Villa Pérez, Cristian
Rafti, Matias
Vega, Isabel Natalia
Giussi, Juan Martín
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv PolyMOFs
Tailored Copolymer Microstructure
Surface-Initiated ATRP
ZIF-8 Growth
Polymeric Template
topic PolyMOFs
Tailored Copolymer Microstructure
Surface-Initiated ATRP
ZIF-8 Growth
Polymeric Template
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv In this work, we report copolymers based on zinc dimethacrylate (ZnDMA) and poly(ethylene glycol)methyl ether methacrylate (PEGMA) as versatile platforms for the in situ growth of ZIF-8 polyMOFs.ZnDMA is a suitable monomer which can potentially optimize polyMOF growth, enabling improvedcontrol over the nucleation process and both final structure and morphology. The copolymers were synthesized both as bulk materials from precursor solutions and via surface-initiated Atom Transfer Radical Polymerization (ATRP). The composition and microstructure were investigated using the Fineman-Ross method, complemented by characterization through X-ray photoelectron spectroscopy (XPS), proton nuclear magnetic resonance (1H NMR), thermogravimetric analysis (TGA), aqueous size exclusion chromatography (SEC) and scanning electron microscopy (SEM). We found that variations in structural stability, composition and microstructure of the resulting poly(ZnDMA-co-PEGMA)@ZIF-8 materials can be traced back to conditions affecting polyMOF growth, mainly regarding efficient nucleation and controlled crystalline growth. Overall, these results demonstrate that the hereby proposed synthetic approach to polyMOFs can be employed for the rational design of functional nanostructured porous materials.
Fil: Legarto, Maria Celeste. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Iborra, Agustín. YPF - Tecnología; Argentina
Fil: Romero, Juan J.. YPF - Tecnología; Argentina
Fil: Padró, Juan M.. YPF - Tecnología; Argentina
Fil: Villa Pérez, Cristian. YPF - Tecnología; Argentina
Fil: Rafti, Matias. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Vega, Isabel Natalia. YPF - Tecnología; Argentina
Fil: Giussi, Juan Martín. YPF - Tecnología; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description In this work, we report copolymers based on zinc dimethacrylate (ZnDMA) and poly(ethylene glycol)methyl ether methacrylate (PEGMA) as versatile platforms for the in situ growth of ZIF-8 polyMOFs.ZnDMA is a suitable monomer which can potentially optimize polyMOF growth, enabling improvedcontrol over the nucleation process and both final structure and morphology. The copolymers were synthesized both as bulk materials from precursor solutions and via surface-initiated Atom Transfer Radical Polymerization (ATRP). The composition and microstructure were investigated using the Fineman-Ross method, complemented by characterization through X-ray photoelectron spectroscopy (XPS), proton nuclear magnetic resonance (1H NMR), thermogravimetric analysis (TGA), aqueous size exclusion chromatography (SEC) and scanning electron microscopy (SEM). We found that variations in structural stability, composition and microstructure of the resulting poly(ZnDMA-co-PEGMA)@ZIF-8 materials can be traced back to conditions affecting polyMOF growth, mainly regarding efficient nucleation and controlled crystalline growth. Overall, these results demonstrate that the hereby proposed synthetic approach to polyMOFs can be employed for the rational design of functional nanostructured porous materials.
publishDate 2026
dc.date.none.fl_str_mv 2026-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/291779
Legarto, Maria Celeste; Iborra, Agustín; Romero, Juan J.; Padró, Juan M.; Villa Pérez, Cristian; et al.; Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth; Royal Society of Chemistry; RSC Applied Polymers; 4; 3; 4-2026; 952-963
2755-371X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/291779
identifier_str_mv Legarto, Maria Celeste; Iborra, Agustín; Romero, Juan J.; Padró, Juan M.; Villa Pérez, Cristian; et al.; Copolymers with tailored microstructure as versatile platforms for ZIF-8 polyMOF growth; Royal Society of Chemistry; RSC Applied Polymers; 4; 3; 4-2026; 952-963
2755-371X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://xlink.rsc.org/?DOI=D6LP00021E
info:eu-repo/semantics/altIdentifier/doi/10.1039/D6LP00021E
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.265058

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