Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS

Autores
Cerqueira Da Silva, Vinnicius; Dirchwolf, Pamela Maia; Hidalgo, Melisa Jazmin; Pellerano, Roberto Gerardo; Zezzi Arruda, Marco
Año de publicación
2025
Idioma
español castellano
Tipo de recurso
documento de conferencia
Estado
versión publicada
Descripción
Riceis a staple crop essential to food security in many countries, includingArgentina, one of the leading producers in Latin America, with an output ofapproximately 1.3 million tons. The Corrientes district stands out as thecountry's leading rice-producing region. However, rice isconsidered one of the primary sources of dietary arsenic (As), as the plant canaccumulate this element in the grain. Arsenic is a toxic element naturallyfound in the Earth's crust and is associated with mutagenic, teratogenic,genotoxic, and neurotoxic effects. This study aimed todevelop a simple, high-throughput analytical method based on high-frequencyultrasound-assisted extraction with diluted nitric acid for determining totalarsenic and its speciation.
Fil: Cerqueira Da Silva, Vinnicius. Universidade Estadual de Campinas; Brasil
Fil: Dirchwolf, Pamela Maia. Universidad Nacional del Nordeste. Facultad de Ciencias Agrarias; Argentina
Fil: Hidalgo, Melisa Jazmin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Zezzi Arruda, Marco. Universidade Estadual de Campinas; Brasil
XIII Congreso Argentino de Química Analítica
San Miguel de Tucumán
Argentina
Asociación Argentina de Química Analítica
Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia
Materia
ARROZ
ARSENICO
DISEÑO EXPERIMENTAL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/290638
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MSCerqueira Da Silva, VinniciusDirchwolf, Pamela MaiaHidalgo, Melisa JazminPellerano, Roberto GerardoZezzi Arruda, MarcoARROZARSENICODISEÑO EXPERIMENTALhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Riceis a staple crop essential to food security in many countries, includingArgentina, one of the leading producers in Latin America, with an output ofapproximately 1.3 million tons. The Corrientes district stands out as thecountry's leading rice-producing region. However, rice isconsidered one of the primary sources of dietary arsenic (As), as the plant canaccumulate this element in the grain. Arsenic is a toxic element naturallyfound in the Earth's crust and is associated with mutagenic, teratogenic,genotoxic, and neurotoxic effects. This study aimed todevelop a simple, high-throughput analytical method based on high-frequencyultrasound-assisted extraction with diluted nitric acid for determining totalarsenic and its speciation.Fil: Cerqueira Da Silva, Vinnicius. Universidade Estadual de Campinas; BrasilFil: Dirchwolf, Pamela Maia. Universidad Nacional del Nordeste. Facultad de Ciencias Agrarias; ArgentinaFil: Hidalgo, Melisa Jazmin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; ArgentinaFil: Zezzi Arruda, Marco. Universidade Estadual de Campinas; BrasilXIII Congreso Argentino de Química AnalíticaSan Miguel de TucumánArgentinaAsociación Argentina de Química AnalíticaUniversidad Nacional de Tucumán. Facultad de Bioquímica, Química y FarmaciaUniversidad Nacional de Tucumán2025info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjectCongresoBookhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciaapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/290638Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS; XIII Congreso Argentino de Química Analítica; San Miguel de Tucumán; Argentina; 2025; 29-29978-631-01-0359-4CONICET DigitalCONICETspainfo:eu-repo/semantics/altIdentifier/url/https://www.aaqa.org.ar/web/congresos/Nacionalinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-08-25T15:00:47Zoai:ri.conicet.gov.ar:11336/290638instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-08-25 15:00:47.559CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
title Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
spellingShingle Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
Cerqueira Da Silva, Vinnicius
ARROZ
ARSENICO
DISEÑO EXPERIMENTAL
title_short Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
title_full Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
title_fullStr Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
title_full_unstemmed Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
title_sort Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS
dc.creator.none.fl_str_mv Cerqueira Da Silva, Vinnicius
Dirchwolf, Pamela Maia
Hidalgo, Melisa Jazmin
Pellerano, Roberto Gerardo
Zezzi Arruda, Marco
author Cerqueira Da Silva, Vinnicius
author_facet Cerqueira Da Silva, Vinnicius
Dirchwolf, Pamela Maia
Hidalgo, Melisa Jazmin
Pellerano, Roberto Gerardo
Zezzi Arruda, Marco
author_role author
author2 Dirchwolf, Pamela Maia
Hidalgo, Melisa Jazmin
Pellerano, Roberto Gerardo
Zezzi Arruda, Marco
author2_role author
author
author
author
dc.subject.none.fl_str_mv ARROZ
ARSENICO
DISEÑO EXPERIMENTAL
topic ARROZ
ARSENICO
DISEÑO EXPERIMENTAL
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Riceis a staple crop essential to food security in many countries, includingArgentina, one of the leading producers in Latin America, with an output ofapproximately 1.3 million tons. The Corrientes district stands out as thecountry's leading rice-producing region. However, rice isconsidered one of the primary sources of dietary arsenic (As), as the plant canaccumulate this element in the grain. Arsenic is a toxic element naturallyfound in the Earth's crust and is associated with mutagenic, teratogenic,genotoxic, and neurotoxic effects. This study aimed todevelop a simple, high-throughput analytical method based on high-frequencyultrasound-assisted extraction with diluted nitric acid for determining totalarsenic and its speciation.
Fil: Cerqueira Da Silva, Vinnicius. Universidade Estadual de Campinas; Brasil
Fil: Dirchwolf, Pamela Maia. Universidad Nacional del Nordeste. Facultad de Ciencias Agrarias; Argentina
Fil: Hidalgo, Melisa Jazmin. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Pellerano, Roberto Gerardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Química Básica y Aplicada del Nordeste Argentino. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas Naturales y Agrimensura. Instituto de Química Básica y Aplicada del Nordeste Argentino; Argentina
Fil: Zezzi Arruda, Marco. Universidade Estadual de Campinas; Brasil
XIII Congreso Argentino de Química Analítica
San Miguel de Tucumán
Argentina
Asociación Argentina de Química Analítica
Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia
description Riceis a staple crop essential to food security in many countries, includingArgentina, one of the leading producers in Latin America, with an output ofapproximately 1.3 million tons. The Corrientes district stands out as thecountry's leading rice-producing region. However, rice isconsidered one of the primary sources of dietary arsenic (As), as the plant canaccumulate this element in the grain. Arsenic is a toxic element naturallyfound in the Earth's crust and is associated with mutagenic, teratogenic,genotoxic, and neurotoxic effects. This study aimed todevelop a simple, high-throughput analytical method based on high-frequencyultrasound-assisted extraction with diluted nitric acid for determining totalarsenic and its speciation.
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/publishedVersion
info:eu-repo/semantics/conferenceObject
Congreso
Book
http://purl.org/coar/resource_type/c_5794
info:ar-repo/semantics/documentoDeConferencia
status_str publishedVersion
format conferenceObject
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/290638
Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS; XIII Congreso Argentino de Química Analítica; San Miguel de Tucumán; Argentina; 2025; 29-29
978-631-01-0359-4
CONICET Digital
CONICET
url http://hdl.handle.net/11336/290638
identifier_str_mv Box-Behnken design in the development of a simple and fast method for the determination of total Arsenic and its species in husked rice (Oryza sativa L.) by ICP-MS and HPLC-ICP-MS; XIII Congreso Argentino de Química Analítica; San Miguel de Tucumán; Argentina; 2025; 29-29
978-631-01-0359-4
CONICET Digital
CONICET
dc.language.none.fl_str_mv spa
language spa
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https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
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dc.coverage.none.fl_str_mv Nacional
dc.publisher.none.fl_str_mv Universidad Nacional de Tucumán
publisher.none.fl_str_mv Universidad Nacional de Tucumán
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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