Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.

Autores
Vallés , Verónica Alejandra; Ledesma , Brenda Cecilia; Rivoira , Lorena Paola; Cussa , jorgelina; Anunziata , Oscar Alfredo; Beltramone, Andrea Raquel; Anunziata , Oscar Alfredo; Cussa , jorgelina; Rivoira , Lorena Paola; Ledesma , Brenda Cecilia
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión aceptada
Descripción
Experiment design-response surface methodology (RSM) is used in this work to model and optimize two responses in the hydrogenation of tetralin to decalin using bimetallic Ir–Pt-SBA-15 catalyst. In this study, we analyze the influence of the nature of the catalyst (metal molar fraction and metal loading), the catalyst/substrate ratio and the temperature of the reaction as factors for the design. The responses analyzed were conversion at 3 h and at 5 h of reaction time. The response surfaces were obtained with the Box– Behnken design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the two objective functions were obtained employing the catalyst with 1 wt.% of iridium and 0.7–0.8 wt.% of platinum; the optimal ratio between mass of catalyst and mole of tetralin was 17–19 g/mol and temperature between 200 and 220 ◦C
Fil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Rivoira, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
Materia
Iridium-Platinum containing SBA-15
Tetralin hydrogenation
Trans/cis ratio
Experimental desing
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Attribution-NonCommercial-NoDerivatives 4.0 International
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/12672
Acceder
id RIAUTN_032bbca99302429d5d6f5e4b58a811b0
oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/12672
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.Vallés , Verónica AlejandraLedesma , Brenda CeciliaRivoira , Lorena PaolaCussa , jorgelinaAnunziata , Oscar AlfredoBeltramone, Andrea RaquelAnunziata , Oscar AlfredoCussa , jorgelinaRivoira , Lorena PaolaLedesma , Brenda CeciliaIridium-Platinum containing SBA-15Tetralin hydrogenationTrans/cis ratioExperimental desingExperiment design-response surface methodology (RSM) is used in this work to model and optimize two responses in the hydrogenation of tetralin to decalin using bimetallic Ir–Pt-SBA-15 catalyst. In this study, we analyze the influence of the nature of the catalyst (metal molar fraction and metal loading), the catalyst/substrate ratio and the temperature of the reaction as factors for the design. The responses analyzed were conversion at 3 h and at 5 h of reaction time. The response surfaces were obtained with the Box– Behnken design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the two objective functions were obtained employing the catalyst with 1 wt.% of iridium and 0.7–0.8 wt.% of platinum; the optimal ratio between mass of catalyst and mole of tetralin was 17–19 g/mol and temperature between 200 and 220 ◦CFil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Rivoira, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Peer ReviewedUnivesidsad Tecnológica Nacional.2025-04-11T19:48:34Z2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfElsevier- Catalysis Today Journal home page, 2015.www.elsevier.com/locate/cattodhttps://hdl.handle.net/20.500.12272/12672enginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia; Rivoira, Lorena Paola; Cussa, Jorgelina; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel.https://creativecommons.org/licenses/by-nc-nd/4.0/reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:48:37Zoai:ria.utn.edu.ar:20.500.12272/12672instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:48:38.774Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
title Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
spellingShingle Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
Vallés , Verónica Alejandra
Iridium-Platinum containing SBA-15
Tetralin hydrogenation
Trans/cis ratio
Experimental desing
title_short Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
title_full Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
title_fullStr Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
title_full_unstemmed Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
title_sort Experimental desing optimization of the tetralin hydrogenation over Ir-Pt-SBA-15.
dc.creator.none.fl_str_mv Vallés , Verónica Alejandra
Ledesma , Brenda Cecilia
Rivoira , Lorena Paola
Cussa , jorgelina
Anunziata , Oscar Alfredo
Beltramone, Andrea Raquel
Anunziata , Oscar Alfredo
Cussa , jorgelina
Rivoira , Lorena Paola
Ledesma , Brenda Cecilia
author Vallés , Verónica Alejandra
author_facet Vallés , Verónica Alejandra
Ledesma , Brenda Cecilia
Rivoira , Lorena Paola
Cussa , jorgelina
Anunziata , Oscar Alfredo
Beltramone, Andrea Raquel
author_role author
author2 Ledesma , Brenda Cecilia
Rivoira , Lorena Paola
Cussa , jorgelina
Anunziata , Oscar Alfredo
Beltramone, Andrea Raquel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Iridium-Platinum containing SBA-15
Tetralin hydrogenation
Trans/cis ratio
Experimental desing
topic Iridium-Platinum containing SBA-15
Tetralin hydrogenation
Trans/cis ratio
Experimental desing
dc.description.none.fl_txt_mv Experiment design-response surface methodology (RSM) is used in this work to model and optimize two responses in the hydrogenation of tetralin to decalin using bimetallic Ir–Pt-SBA-15 catalyst. In this study, we analyze the influence of the nature of the catalyst (metal molar fraction and metal loading), the catalyst/substrate ratio and the temperature of the reaction as factors for the design. The responses analyzed were conversion at 3 h and at 5 h of reaction time. The response surfaces were obtained with the Box– Behnken design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the two objective functions were obtained employing the catalyst with 1 wt.% of iridium and 0.7–0.8 wt.% of platinum; the optimal ratio between mass of catalyst and mole of tetralin was 17–19 g/mol and temperature between 200 and 220 ◦C
Fil: Vallés, Verónica Alejandra. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Rivoira, Lorena Paola. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
description Experiment design-response surface methodology (RSM) is used in this work to model and optimize two responses in the hydrogenation of tetralin to decalin using bimetallic Ir–Pt-SBA-15 catalyst. In this study, we analyze the influence of the nature of the catalyst (metal molar fraction and metal loading), the catalyst/substrate ratio and the temperature of the reaction as factors for the design. The responses analyzed were conversion at 3 h and at 5 h of reaction time. The response surfaces were obtained with the Box– Behnken design, finding the best combination between the reaction parameters that allowed optimizing the process. By applying the statistic methodology, the higher levels of the two objective functions were obtained employing the catalyst with 1 wt.% of iridium and 0.7–0.8 wt.% of platinum; the optimal ratio between mass of catalyst and mole of tetralin was 17–19 g/mol and temperature between 200 and 220 ◦C
publishDate 2015
dc.date.none.fl_str_mv 2015
2025-04-11T19:48:34Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv Elsevier- Catalysis Today Journal home page, 2015.
www.elsevier.com/locate/cattod
https://hdl.handle.net/20.500.12272/12672
identifier_str_mv Elsevier- Catalysis Today Journal home page, 2015.
www.elsevier.com/locate/cattod
url https://hdl.handle.net/20.500.12272/12672
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia; Rivoira, Lorena Paola; Cussa, Jorgelina; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel.
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Vallés, Verónica Alejandra; Ledesma, Brenda Cecilia; Rivoira, Lorena Paola; Cussa, Jorgelina; Anunziata, Oscar Alfredo; Beltramone, Andrea Raquel.
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.publisher.none.fl_str_mv Univesidsad Tecnológica Nacional.
publisher.none.fl_str_mv Univesidsad Tecnológica Nacional.
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
_version_ 1877230969656705024
score 13.265058

Publicaciones similares