Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass

Autores
Tourn, Silvana; Saires, Paula; Bertero, Melisa; Falco, Marisa; Chamorro, Ester R.
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Tourn, Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. lnstituto de Modelado e Innovación Tecnológica; Argentina.
Fil: Saires, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Bertero, Melisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Falco, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Chamorro, Ester R. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Chamorro, Ester R. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Modelado e Innovación Tecnológica; Argentina.
Peer Reviewed
Materia
lignocellulosic residues
pyrolysis
bio-oil
tar
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2023-11-21T20:32:44Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/8875
Acceder
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network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomassTourn, SilvanaSaires, PaulaBertero, MelisaFalco, MarisaChamorro, Ester R.lignocellulosic residuespyrolysisbio-oiltarPyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Tourn, Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. lnstituto de Modelado e Innovación Tecnológica; Argentina.Fil: Saires, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.Fil: Bertero, Melisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.Fil: Falco, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.Fil: Chamorro, Ester R. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Chamorro, Ester R. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Modelado e Innovación Tecnológica; Argentina.Peer Reviewed2023-11-21T20:32:44Z2023-11-21T20:32:44Z2023-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttp://hdl.handle.net/20.500.12272/887510.18282/pef.v12i1.3333enginfo:eu-repo/semantics/openAccess2023-11-21T20:32:44ZAcceso abiertoreponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-10-01T11:57:39Zoai:ria.utn.edu.ar:20.500.12272/8875instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-10-01 11:57:40.351Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
spellingShingle Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
Tourn, Silvana
lignocellulosic residues
pyrolysis
bio-oil
tar
title_short Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_full Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_fullStr Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_full_unstemmed Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
title_sort Developing alternatives to hydrocarbon via pyrolysis and gasification of industry residual biomass
dc.creator.none.fl_str_mv Tourn, Silvana
Saires, Paula
Bertero, Melisa
Falco, Marisa
Chamorro, Ester R.
author Tourn, Silvana
author_facet Tourn, Silvana
Saires, Paula
Bertero, Melisa
Falco, Marisa
Chamorro, Ester R.
author_role author
author2 Saires, Paula
Bertero, Melisa
Falco, Marisa
Chamorro, Ester R.
author2_role author
author
author
author
dc.subject.none.fl_str_mv lignocellulosic residues
pyrolysis
bio-oil
tar
topic lignocellulosic residues
pyrolysis
bio-oil
tar
dc.description.none.fl_txt_mv Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Tourn, Silvana. Consejo Nacional de Investigaciones Científicas y Técnicas. lnstituto de Modelado e Innovación Tecnológica; Argentina.
Fil: Saires, Paula. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Bertero, Melisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Falco, Marisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica; Argentina.
Fil: Chamorro, Ester R. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina. Fil: Chamorro, Ester R. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Modelado e Innovación Tecnológica; Argentina.
Peer Reviewed
description Pyrolysis and gasification are thermal treatment processes using biomass to produce biofuels that can replace fossil fuels in industrial boilers and furnaces. This paper discusses the potential utilization of four types of residual biomass highly produced in the Argentina Northeast (NEA) region, i.e., rice husk, an agricultural waste rich in cotton husk, carob sawdust, and spent red quebracho sawdust, as raw material. Pyrolysis liquid product yields were 34–51 wt% and char yields were 29–40 wt%; tar represented 16–23 wt%. For gasification, gas yields were between 45.6 wt% and 65.7 wt%; as for tar, it represented 2.4–14.1 wt% of initial biomass, and char yields were 31.4–40.3 wt%. Characterization of all products was performed to clarify their potential applications. Bio-oils, i.e., aqueous fractions of pyrolysis liquid products, have high water content (77–88 wt%), that is why they have lower density and viscosity than tars, oil fractions of pyrolysis liquids. However, chemical stability of bio-oils may vary, and their heating values are much lower than the heating values from tars. Based on these, it is possible to concluded that tar is the product with increased added value and higher energy properties. Efficiency of gasification and heating values of the gases obtained were high for waste rich in cotton husk and spent red quebracho sawdust, suggesting a good potential for the utilization in gasification processes. Additionally, char composition and properties for all biomasses, from both process, show that it is feasible to use them in several new applications.
publishDate 2023
dc.date.none.fl_str_mv 2023-11-21T20:32:44Z
2023-11-21T20:32:44Z
2023-08-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/8875
10.18282/pef.v12i1.3333
url http://hdl.handle.net/20.500.12272/8875
identifier_str_mv 10.18282/pef.v12i1.3333
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2023-11-21T20:32:44Z
Acceso abierto
eu_rights_str_mv openAccess
rights_invalid_str_mv 2023-11-21T20:32:44Z
Acceso abierto
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.365483

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