Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production

Autores
Rivoira, Lorena; Ledesma, Brenda; Fraire, María; Valles , Verónica; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Platinum-modified activated carbon was synthesized and studied for hydrodeoxygenation (HDO) of guaiacol. The activated carbon support was prepared using orange peel from industrial waste. Platinum was added by wetness impregnation. The activity was compared with that of platinum supported on mesoporous silica and commercial activated carbon catalysts. The catalysts prepared were characterized by different techniques: XRD and N2 adsorption isotherms to confirm the mesoporous structure, and XPS, H2-Chemisorption and Boehm titration to determine active sites and acidity. The results showed thathigh-surface-area active carbon support favors the formation of small platinum metallic particles, highly dispersed over the surface. The catalysts were active for guaiacol HDO performed in the laboratory at 200 °C and 12 atm of H2 in a Batch PARR reactor. Carbon was activated using phosphoric acid during the synthesis. The interaction between the peculiar acidity generated on the support by H3PO4, accompanied by the high hydrogenation capacity of the metallic platinum particles, enhanced catalytic activity, and selectivity for deoxygenated products. The most acidic-activated carbon support modified with 0.5 wt% of platinum was the most active catalyst in the HDO of guaiacol, reaching 88 mol% of guaiacol conversion and selectivity of 78% toward HDO products such as phenol, benzene and cyclohexane. The novelty of this research aims at developing an environmentally friendly catalyst to produce biomolecules of high aggregated value at mild reaction conditions reducing energy consumption.
Fil: Gómez Costa, Marcos bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Rivoira, Lorena. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Fraire, María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Valles, Verónica. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
Fuente
Volumen 27 , páginas 4289–4309 ( 2025 )
Materia
HDO
Activated carbon
Biomass
Platinum
Benzene
Cyclohexame
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Attribution-NonCommercial-NoDerivs 2.5 Argentina
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/15520
Acceder
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oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/15520
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel productionRivoira, LorenaLedesma, BrendaFraire, MaríaValles , VerónicaGómez Costa, Marcos BrunoBeltramone, Andrea RaquelHDOActivated carbonBiomassPlatinumBenzeneCyclohexamePlatinum-modified activated carbon was synthesized and studied for hydrodeoxygenation (HDO) of guaiacol. The activated carbon support was prepared using orange peel from industrial waste. Platinum was added by wetness impregnation. The activity was compared with that of platinum supported on mesoporous silica and commercial activated carbon catalysts. The catalysts prepared were characterized by different techniques: XRD and N2 adsorption isotherms to confirm the mesoporous structure, and XPS, H2-Chemisorption and Boehm titration to determine active sites and acidity. The results showed thathigh-surface-area active carbon support favors the formation of small platinum metallic particles, highly dispersed over the surface. The catalysts were active for guaiacol HDO performed in the laboratory at 200 °C and 12 atm of H2 in a Batch PARR reactor. Carbon was activated using phosphoric acid during the synthesis. The interaction between the peculiar acidity generated on the support by H3PO4, accompanied by the high hydrogenation capacity of the metallic platinum particles, enhanced catalytic activity, and selectivity for deoxygenated products. The most acidic-activated carbon support modified with 0.5 wt% of platinum was the most active catalyst in the HDO of guaiacol, reaching 88 mol% of guaiacol conversion and selectivity of 78% toward HDO products such as phenol, benzene and cyclohexane. The novelty of this research aims at developing an environmentally friendly catalyst to produce biomolecules of high aggregated value at mild reaction conditions reducing energy consumption.Fil: Gómez Costa, Marcos bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Rivoira, Lorena. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Fraire, María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Valles, Verónica. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Peer ReviewedSpringer2026-09-11T19:05:14Z2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfClean Technologies and Environmental Policyhttps://hdl.handle.net/20.500.12272/15520https://doi.org/10.1007/s10098-024-03119-zVolumen 27 , páginas 4289–4309 ( 2025 )reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacionalenginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivs 2.5 Argentinahttp://creativecommons.org/licenses/by-nc-nd/2.5/ar/Rivoira, Lorena; Ledesma, Brenda; Fraire, María; Valles, Verónica; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel.https://creativecommons.org/licenses/by-nc-nd/4.0/2026-09-24T12:45:55Zoai:ria.utn.edu.ar:20.500.12272/15520instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:45:56.579Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
title Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
spellingShingle Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
Rivoira, Lorena
HDO
Activated carbon
Biomass
Platinum
Benzene
Cyclohexame
title_short Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
title_full Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
title_fullStr Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
title_full_unstemmed Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
title_sort Biomass waste as a raw material for the meosoporous catalyst synthesis and its application in HDO of guaiacol for biofuel production
dc.creator.none.fl_str_mv Rivoira, Lorena
Ledesma, Brenda
Fraire, María
Valles , Verónica
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author Rivoira, Lorena
author_facet Rivoira, Lorena
Ledesma, Brenda
Fraire, María
Valles , Verónica
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author_role author
author2 Ledesma, Brenda
Fraire, María
Valles , Verónica
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv HDO
Activated carbon
Biomass
Platinum
Benzene
Cyclohexame
topic HDO
Activated carbon
Biomass
Platinum
Benzene
Cyclohexame
dc.description.none.fl_txt_mv Platinum-modified activated carbon was synthesized and studied for hydrodeoxygenation (HDO) of guaiacol. The activated carbon support was prepared using orange peel from industrial waste. Platinum was added by wetness impregnation. The activity was compared with that of platinum supported on mesoporous silica and commercial activated carbon catalysts. The catalysts prepared were characterized by different techniques: XRD and N2 adsorption isotherms to confirm the mesoporous structure, and XPS, H2-Chemisorption and Boehm titration to determine active sites and acidity. The results showed thathigh-surface-area active carbon support favors the formation of small platinum metallic particles, highly dispersed over the surface. The catalysts were active for guaiacol HDO performed in the laboratory at 200 °C and 12 atm of H2 in a Batch PARR reactor. Carbon was activated using phosphoric acid during the synthesis. The interaction between the peculiar acidity generated on the support by H3PO4, accompanied by the high hydrogenation capacity of the metallic platinum particles, enhanced catalytic activity, and selectivity for deoxygenated products. The most acidic-activated carbon support modified with 0.5 wt% of platinum was the most active catalyst in the HDO of guaiacol, reaching 88 mol% of guaiacol conversion and selectivity of 78% toward HDO products such as phenol, benzene and cyclohexane. The novelty of this research aims at developing an environmentally friendly catalyst to produce biomolecules of high aggregated value at mild reaction conditions reducing energy consumption.
Fil: Gómez Costa, Marcos bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Rivoira, Lorena. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Fraire, María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Valles, Verónica. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
description Platinum-modified activated carbon was synthesized and studied for hydrodeoxygenation (HDO) of guaiacol. The activated carbon support was prepared using orange peel from industrial waste. Platinum was added by wetness impregnation. The activity was compared with that of platinum supported on mesoporous silica and commercial activated carbon catalysts. The catalysts prepared were characterized by different techniques: XRD and N2 adsorption isotherms to confirm the mesoporous structure, and XPS, H2-Chemisorption and Boehm titration to determine active sites and acidity. The results showed thathigh-surface-area active carbon support favors the formation of small platinum metallic particles, highly dispersed over the surface. The catalysts were active for guaiacol HDO performed in the laboratory at 200 °C and 12 atm of H2 in a Batch PARR reactor. Carbon was activated using phosphoric acid during the synthesis. The interaction between the peculiar acidity generated on the support by H3PO4, accompanied by the high hydrogenation capacity of the metallic platinum particles, enhanced catalytic activity, and selectivity for deoxygenated products. The most acidic-activated carbon support modified with 0.5 wt% of platinum was the most active catalyst in the HDO of guaiacol, reaching 88 mol% of guaiacol conversion and selectivity of 78% toward HDO products such as phenol, benzene and cyclohexane. The novelty of this research aims at developing an environmentally friendly catalyst to produce biomolecules of high aggregated value at mild reaction conditions reducing energy consumption.
publishDate 2024
dc.date.none.fl_str_mv 2024
2026-09-11T19:05:14Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv Clean Technologies and Environmental Policy
https://hdl.handle.net/20.500.12272/15520
https://doi.org/10.1007/s10098-024-03119-z
identifier_str_mv Clean Technologies and Environmental Policy
url https://hdl.handle.net/20.500.12272/15520
https://doi.org/10.1007/s10098-024-03119-z
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivs 2.5 Argentina
http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Rivoira, Lorena; Ledesma, Brenda; Fraire, María; Valles, Verónica; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel.
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivs 2.5 Argentina
http://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Rivoira, Lorena; Ledesma, Brenda; Fraire, María; Valles, Verónica; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel.
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv Volumen 27 , páginas 4289–4309 ( 2025 )
reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
_version_ 1877230912249266176
score 13.265058

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