Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix

Autores
Cáceres, Liliana Mariel; Tourn, Silvana; Ruiz, Carlos Raúl; Sequeira, Alfredo Fabián; Dagnino, Eliana Paola
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The increase in the rate of production and accumulation of solid waste and the search for sustainable environmental solutions imposes the need to introduce advanced technologies to manage it efficiently. In this context, this work aims to obtain carboxymethylcellulose (CMC) from lignocellulosic waste and later use it in the encapsulation of liquid smoke and essential oils. Thus, a product of higher value can be obtained from an abundant and readably available waste product of northeastern Argentina`s agroforestal industry. Rice husk samples for this research were provided by a local company. The rice husk was treated in a biorefinery scheme (Acid hydrolysis, 0.3% w/V, 150°C, 30 min; followed by organosolv treatment, NaOH-ethanol-water, 160°C, 60min, and alkaline treatment). Subsequently, CMC was obtained, esterifying the unbleached cellulose obtained from the mentioned raw material, using a modification of the Druvacell method. The unbleached cellulose is pretreated with isopropanol and sodium hydroxide to promote fiber swelling and ionization of hydroxyl groups, and subsequently esterification with monochloroacetic acid. On the other hand, bio-oil was obtained by pyrolysis, at 400 °C for 120 min, from exhausted Schinopsis balansae (quebracho colorado) sawdust and the water-soluble fraction produced was refined, representing 34.6% based on the residual biomass fed. Finally, the refined fraction was characterized, to identify the improvement and its quality as liquid smoke to be encapsulated. The CMC obtained was used as a component, together with sodium alginate, of a biopolymeric matrix to encapsulate the water-soluble liquid smoke and hydrophobic essential oil. The raw material was characterized by determining its structural components, the substituent groups in CMC were recognized by FTIR and the degree of substitution was determined. In the production of microcapsules, using standard methods the performance and efficiency of the process were determined. On the other hand, the post-treatment rice husk is composed of 94% cellulose, and the rest is lignin and remaining inorganics. From it, it was possible to obtain a crude CMC with a purity greater than 70% and a degree of substitution greater than 0.6. The microencapsulation results show average yields greater than 55% and efficiencies greater than 90% for both encapsulated substances. With this work carried out, a very abundant residue could be valorized by obtaining CMC and using it in the microencapsulation of two chemically different substances. Good yields and efficiencies were obtained with liquid smoke [1] and essential oil [2], with comparable results with other authors.
Fil: Cáceres, Liliana Mariel. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Ruiz, Carlos Raúl. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Sequeira, Alfredo Fabián. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Dagnino, Eliana Paola. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Peer Reviewed
Materia
Carboxymethylcellulose
lignocellulosic
liquid smoke
microencapsulation
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2024-03-25T21:11:40Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/10060
Acceder
id RIAUTN_6a5d0af83cef191c80ecd68f6664f51f
oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/10060
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrixCáceres, Liliana MarielTourn, SilvanaRuiz, Carlos RaúlSequeira, Alfredo FabiánDagnino, Eliana PaolaCarboxymethylcelluloselignocellulosicliquid smokemicroencapsulationThe increase in the rate of production and accumulation of solid waste and the search for sustainable environmental solutions imposes the need to introduce advanced technologies to manage it efficiently. In this context, this work aims to obtain carboxymethylcellulose (CMC) from lignocellulosic waste and later use it in the encapsulation of liquid smoke and essential oils. Thus, a product of higher value can be obtained from an abundant and readably available waste product of northeastern Argentina`s agroforestal industry. Rice husk samples for this research were provided by a local company. The rice husk was treated in a biorefinery scheme (Acid hydrolysis, 0.3% w/V, 150°C, 30 min; followed by organosolv treatment, NaOH-ethanol-water, 160°C, 60min, and alkaline treatment). Subsequently, CMC was obtained, esterifying the unbleached cellulose obtained from the mentioned raw material, using a modification of the Druvacell method. The unbleached cellulose is pretreated with isopropanol and sodium hydroxide to promote fiber swelling and ionization of hydroxyl groups, and subsequently esterification with monochloroacetic acid. On the other hand, bio-oil was obtained by pyrolysis, at 400 °C for 120 min, from exhausted Schinopsis balansae (quebracho colorado) sawdust and the water-soluble fraction produced was refined, representing 34.6% based on the residual biomass fed. Finally, the refined fraction was characterized, to identify the improvement and its quality as liquid smoke to be encapsulated. The CMC obtained was used as a component, together with sodium alginate, of a biopolymeric matrix to encapsulate the water-soluble liquid smoke and hydrophobic essential oil. The raw material was characterized by determining its structural components, the substituent groups in CMC were recognized by FTIR and the degree of substitution was determined. In the production of microcapsules, using standard methods the performance and efficiency of the process were determined. On the other hand, the post-treatment rice husk is composed of 94% cellulose, and the rest is lignin and remaining inorganics. From it, it was possible to obtain a crude CMC with a purity greater than 70% and a degree of substitution greater than 0.6. The microencapsulation results show average yields greater than 55% and efficiencies greater than 90% for both encapsulated substances. With this work carried out, a very abundant residue could be valorized by obtaining CMC and using it in the microencapsulation of two chemically different substances. Good yields and efficiencies were obtained with liquid smoke [1] and essential oil [2], with comparable results with other authors.Fil: Cáceres, Liliana Mariel. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.Fil: Ruiz, Carlos Raúl. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.Fil: Sequeira, Alfredo Fabián. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.Fil: Dagnino, Eliana Paola. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.Peer Reviewed2024-03-25T21:11:40Z2024-03-25T21:11:40Z2023-06-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdf11th World Congress of Chemical Engineering WCCE112953-5565http://hdl.handle.net/20.500.12272/10060engengProducción de microcápsulas a partir de polímeros provenientes de la producción agro-foresto-industrial del NEAPAUTIRE0007698TCinfo:eu-repo/semantics/openAccess2024-03-25T21:11:40Zhttp://creativecommons.org/licenses/by-nc-sa/4.0/Atribución-NoComercial-CompartirIgual 4.0 InternacionalAcceso abiertoreponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:45:53Zoai:ria.utn.edu.ar:20.500.12272/10060instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:45:54.539Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
title Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
spellingShingle Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
Cáceres, Liliana Mariel
Carboxymethylcellulose
lignocellulosic
liquid smoke
microencapsulation
title_short Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
title_full Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
title_fullStr Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
title_full_unstemmed Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
title_sort Carboxymethylcellulose obtained from lignocellulosic waste and its use as a biopolymeric matrix
dc.creator.none.fl_str_mv Cáceres, Liliana Mariel
Tourn, Silvana
Ruiz, Carlos Raúl
Sequeira, Alfredo Fabián
Dagnino, Eliana Paola
author Cáceres, Liliana Mariel
author_facet Cáceres, Liliana Mariel
Tourn, Silvana
Ruiz, Carlos Raúl
Sequeira, Alfredo Fabián
Dagnino, Eliana Paola
author_role author
author2 Tourn, Silvana
Ruiz, Carlos Raúl
Sequeira, Alfredo Fabián
Dagnino, Eliana Paola
author2_role author
author
author
author
dc.subject.none.fl_str_mv Carboxymethylcellulose
lignocellulosic
liquid smoke
microencapsulation
topic Carboxymethylcellulose
lignocellulosic
liquid smoke
microencapsulation
dc.description.none.fl_txt_mv The increase in the rate of production and accumulation of solid waste and the search for sustainable environmental solutions imposes the need to introduce advanced technologies to manage it efficiently. In this context, this work aims to obtain carboxymethylcellulose (CMC) from lignocellulosic waste and later use it in the encapsulation of liquid smoke and essential oils. Thus, a product of higher value can be obtained from an abundant and readably available waste product of northeastern Argentina`s agroforestal industry. Rice husk samples for this research were provided by a local company. The rice husk was treated in a biorefinery scheme (Acid hydrolysis, 0.3% w/V, 150°C, 30 min; followed by organosolv treatment, NaOH-ethanol-water, 160°C, 60min, and alkaline treatment). Subsequently, CMC was obtained, esterifying the unbleached cellulose obtained from the mentioned raw material, using a modification of the Druvacell method. The unbleached cellulose is pretreated with isopropanol and sodium hydroxide to promote fiber swelling and ionization of hydroxyl groups, and subsequently esterification with monochloroacetic acid. On the other hand, bio-oil was obtained by pyrolysis, at 400 °C for 120 min, from exhausted Schinopsis balansae (quebracho colorado) sawdust and the water-soluble fraction produced was refined, representing 34.6% based on the residual biomass fed. Finally, the refined fraction was characterized, to identify the improvement and its quality as liquid smoke to be encapsulated. The CMC obtained was used as a component, together with sodium alginate, of a biopolymeric matrix to encapsulate the water-soluble liquid smoke and hydrophobic essential oil. The raw material was characterized by determining its structural components, the substituent groups in CMC were recognized by FTIR and the degree of substitution was determined. In the production of microcapsules, using standard methods the performance and efficiency of the process were determined. On the other hand, the post-treatment rice husk is composed of 94% cellulose, and the rest is lignin and remaining inorganics. From it, it was possible to obtain a crude CMC with a purity greater than 70% and a degree of substitution greater than 0.6. The microencapsulation results show average yields greater than 55% and efficiencies greater than 90% for both encapsulated substances. With this work carried out, a very abundant residue could be valorized by obtaining CMC and using it in the microencapsulation of two chemically different substances. Good yields and efficiencies were obtained with liquid smoke [1] and essential oil [2], with comparable results with other authors.
Fil: Cáceres, Liliana Mariel. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Tourn, Silvana. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Ruiz, Carlos Raúl. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Sequeira, Alfredo Fabián. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Fil: Dagnino, Eliana Paola. Universidad Tecnológica Nacional. Facultad Regional Resistencia. Centro de Investigación en Química Orgánica Biológica; Argentina.
Peer Reviewed
description The increase in the rate of production and accumulation of solid waste and the search for sustainable environmental solutions imposes the need to introduce advanced technologies to manage it efficiently. In this context, this work aims to obtain carboxymethylcellulose (CMC) from lignocellulosic waste and later use it in the encapsulation of liquid smoke and essential oils. Thus, a product of higher value can be obtained from an abundant and readably available waste product of northeastern Argentina`s agroforestal industry. Rice husk samples for this research were provided by a local company. The rice husk was treated in a biorefinery scheme (Acid hydrolysis, 0.3% w/V, 150°C, 30 min; followed by organosolv treatment, NaOH-ethanol-water, 160°C, 60min, and alkaline treatment). Subsequently, CMC was obtained, esterifying the unbleached cellulose obtained from the mentioned raw material, using a modification of the Druvacell method. The unbleached cellulose is pretreated with isopropanol and sodium hydroxide to promote fiber swelling and ionization of hydroxyl groups, and subsequently esterification with monochloroacetic acid. On the other hand, bio-oil was obtained by pyrolysis, at 400 °C for 120 min, from exhausted Schinopsis balansae (quebracho colorado) sawdust and the water-soluble fraction produced was refined, representing 34.6% based on the residual biomass fed. Finally, the refined fraction was characterized, to identify the improvement and its quality as liquid smoke to be encapsulated. The CMC obtained was used as a component, together with sodium alginate, of a biopolymeric matrix to encapsulate the water-soluble liquid smoke and hydrophobic essential oil. The raw material was characterized by determining its structural components, the substituent groups in CMC were recognized by FTIR and the degree of substitution was determined. In the production of microcapsules, using standard methods the performance and efficiency of the process were determined. On the other hand, the post-treatment rice husk is composed of 94% cellulose, and the rest is lignin and remaining inorganics. From it, it was possible to obtain a crude CMC with a purity greater than 70% and a degree of substitution greater than 0.6. The microencapsulation results show average yields greater than 55% and efficiencies greater than 90% for both encapsulated substances. With this work carried out, a very abundant residue could be valorized by obtaining CMC and using it in the microencapsulation of two chemically different substances. Good yields and efficiencies were obtained with liquid smoke [1] and essential oil [2], with comparable results with other authors.
publishDate 2023
dc.date.none.fl_str_mv 2023-06-04
2024-03-25T21:11:40Z
2024-03-25T21:11:40Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv 11th World Congress of Chemical Engineering WCCE11
2953-5565
http://hdl.handle.net/20.500.12272/10060
identifier_str_mv 11th World Congress of Chemical Engineering WCCE11
2953-5565
url http://hdl.handle.net/20.500.12272/10060
dc.language.none.fl_str_mv eng
eng
language eng
dc.relation.none.fl_str_mv Producción de microcápsulas a partir de polímeros provenientes de la producción agro-foresto-industrial del NEA
PAUTIRE0007698TC
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2024-03-25T21:11:40Z
http://creativecommons.org/licenses/by-nc-sa/4.0/
Atribución-NoComercial-CompartirIgual 4.0 Internacional
Acceso abierto
eu_rights_str_mv openAccess
rights_invalid_str_mv 2024-03-25T21:11:40Z
http://creativecommons.org/licenses/by-nc-sa/4.0/
Atribución-NoComercial-CompartirIgual 4.0 Internacional
Acceso abierto
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.265058

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