Biofuel production using ordered mesoporous carbons with modified carbonaceous structure

Autores
Ledesma, Brenda C.; Beltramone, Andrea R.
Año de publicación
2021
Idioma
inglés
Tipo de recurso
documento de conferencia
Estado
versión publicada
Descripción
Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done in order to understand structure-activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
Fil: Ledesma, Brenda C.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Materia
Titanium
platinum
iridium
modified mesoporous carbon
5-hydroximethylfurfural
2,5-dimethylfuran provide
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2022-06-03T23:03:19Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/6606
Acceder
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network_acronym_str RIAUTN
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network_name_str Repositorio Institucional Abierto (UTN)
spelling Biofuel production using ordered mesoporous carbons with modified carbonaceous structureLedesma, Brenda C.Beltramone, Andrea R.Titaniumplatinumiridiummodified mesoporous carbon5-hydroximethylfurfural2,5-dimethylfuran provideMonometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done in order to understand structure-activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.Fil: Ledesma, Brenda C.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.2022-06-03T23:03:19Z2022-06-03T23:03:19Z2021info:eu-repo/semantics/conferenceObjectinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciapdfapplication/pdfhttp://hdl.handle.net/20.500.12272/6606-enginfo:eu-repo/semantics/openAccess2022-06-03T23:03:19Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalAndrea R. Beltramone_X_Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). _X_No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. _X_Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.). _X_Compartir igual (Share Alike): La explotación autorizada incluye la creación de obras derivadas siempre que se mantenga la misma licencia al ser divulgadas.reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:48:18Zoai:ria.utn.edu.ar:20.500.12272/6606instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:48:19.264Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
title Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
spellingShingle Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
Ledesma, Brenda C.
Titanium
platinum
iridium
modified mesoporous carbon
5-hydroximethylfurfural
2,5-dimethylfuran provide
title_short Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
title_full Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
title_fullStr Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
title_full_unstemmed Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
title_sort Biofuel production using ordered mesoporous carbons with modified carbonaceous structure
dc.creator.none.fl_str_mv Ledesma, Brenda C.
Beltramone, Andrea R.
author Ledesma, Brenda C.
author_facet Ledesma, Brenda C.
Beltramone, Andrea R.
author_role author
author2 Beltramone, Andrea R.
author2_role author
dc.subject.none.fl_str_mv Titanium
platinum
iridium
modified mesoporous carbon
5-hydroximethylfurfural
2,5-dimethylfuran provide
topic Titanium
platinum
iridium
modified mesoporous carbon
5-hydroximethylfurfural
2,5-dimethylfuran provide
dc.description.none.fl_txt_mv Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done in order to understand structure-activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
Fil: Ledesma, Brenda C.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
description Monometallic and bimetallic supported catalysts were developed to produce 2,5-dimethylfuran (DMF) trough hydrogenolysis of 5-(hydroxymethyl)furfural (HMF). Detailed physicochemical characterization was done in order to understand structure-activity correlation. Through a series of experiments and comparatives tests, the synergistic effect among Pt, Ir, and Ti incorporated in the support was investigated. Results revealed that using the titanium contained ordered mesoporous carbon, synthesized by a novel technique, high selectivity to DMF was achieved. In the case of the best catalyst PtIr-TiC, the good activity and excellent selectivity to the desired product DMF (98% yield) was related to the high hydrogenating capacity of the bimetallic sites, the acid support characteristics and the high metal nanoparticles dispersion achieved on the mesoporous titanium modified carbon support.
publishDate 2021
dc.date.none.fl_str_mv 2021
2022-06-03T23:03:19Z
2022-06-03T23:03:19Z
dc.type.none.fl_str_mv info:eu-repo/semantics/conferenceObject
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_5794
info:ar-repo/semantics/documentoDeConferencia
format conferenceObject
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/6606
-
url http://hdl.handle.net/20.500.12272/6606
identifier_str_mv -
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2022-06-03T23:03:19Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Andrea R. Beltramone
_X_Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). _X_No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. _X_Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.). _X_Compartir igual (Share Alike): La explotación autorizada incluye la creación de obras derivadas siempre que se mantenga la misma licencia al ser divulgadas.
eu_rights_str_mv openAccess
rights_invalid_str_mv 2022-06-03T23:03:19Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Andrea R. Beltramone
_X_Atribución (Attribution): En cualquier explotación de la obra autorizada por la licencia será necesario reconocer la autoría (obligatoria en todos los casos). _X_No comercial (Non Commercial): La explotación de la obra queda limitada a usos no comerciales. _X_Sin obras derivadas (No Derivate Works): La autorización para explotar la obra no incluye la posibilidad de crear una obra derivada (traducciones, adaptaciones, etc.). _X_Compartir igual (Share Alike): La explotación autorizada incluye la creación de obras derivadas siempre que se mantenga la misma licencia al ser divulgadas.
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.265058

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