Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……

Autores
Benzaquén, Tamara; Barrera Díaz, Deicy Amparo; Sapag, Karim; Alfano, Orlando; Eimer, Griselda Alejandra
Año de publicación
2017
Idioma
inglés
Tipo de recurso
documento de conferencia
Estado
versión publicada
Descripción
SBA-15 and KIT-6 materials have been synthesized and modified with iron salts by the wet impregnation method with different metal loadings. The different mesostructures obtained were characterized by N2 adsorption-desorption at 77 K, TPR and UVVIS-RD. These iron-containing mesostructured materials have been successfully tested for the heterogeneous photo-Fenton degradation of atrazine (ATZ) aqueous solutions using UV-visible irradiation at room temperature and close to neutral pH. Depending on the dispersion and size of the different iron species, the nanocomposites showed different catalytic behaviors. The results showed that the Fe/SBA-15(10) and Fe/KIT-6(5) catalysts exhibited the highest activities. Thus, the high performance of these materials indicates that the heterogeneous via of photo-Fenton process can also be efficiently employed to treat wastewaters containing pollutants such as herbicides, in order to reduce them to simpler and less toxic molecules.
Fil: Benzaquén, Tamara. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.
Fil: Barrera Díaz, Deicy Amparo. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.
Fil: Sapag, Karim. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.
Fil: Alfano, Orlando. Universidad Nacional del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina.
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.
Materia
Nano-structured catalysts
Heterogeneous photo-fenton process
Degradation of herbicides in aqueous phase.
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2022-05-27T18:07:04Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/6487

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spelling Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……Benzaquén, TamaraBarrera Díaz, Deicy AmparoSapag, KarimAlfano, OrlandoEimer, Griselda AlejandraNano-structured catalystsHeterogeneous photo-fenton processDegradation of herbicides in aqueous phase.SBA-15 and KIT-6 materials have been synthesized and modified with iron salts by the wet impregnation method with different metal loadings. The different mesostructures obtained were characterized by N2 adsorption-desorption at 77 K, TPR and UVVIS-RD. These iron-containing mesostructured materials have been successfully tested for the heterogeneous photo-Fenton degradation of atrazine (ATZ) aqueous solutions using UV-visible irradiation at room temperature and close to neutral pH. Depending on the dispersion and size of the different iron species, the nanocomposites showed different catalytic behaviors. The results showed that the Fe/SBA-15(10) and Fe/KIT-6(5) catalysts exhibited the highest activities. Thus, the high performance of these materials indicates that the heterogeneous via of photo-Fenton process can also be efficiently employed to treat wastewaters containing pollutants such as herbicides, in order to reduce them to simpler and less toxic molecules.Fil: Benzaquén, Tamara. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.Fil: Barrera Díaz, Deicy Amparo. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.Fil: Sapag, Karim. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.Fil: Alfano, Orlando. Universidad Nacional del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina.Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.2022-05-27T18:07:04Z2022-05-27T18:07:04Z2017info:eu-repo/semantics/conferenceObjectinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciapdfapplication/pdf3rd Iberoamerican Conference on Advanced Oxidation Technologies (2017).http://hdl.handle.net/20.500.12272/6487enginfo:eu-repo/semantics/openAccess2022-05-27T18:07:04Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalEimer, Griselda AlejandraNo comercial. Sólo de uso académico.reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-10-01T11:58:01Zoai:ria.utn.edu.ar:20.500.12272/6487instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-10-01 11:58:02.787Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
title Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
spellingShingle Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
Benzaquén, Tamara
Nano-structured catalysts
Heterogeneous photo-fenton process
Degradation of herbicides in aqueous phase.
title_short Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
title_full Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
title_fullStr Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
title_full_unstemmed Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
title_sort Nano-structured catalysts applied to heterogeneous photo-fenton process to degrade herbicides in aqueous phase ……
dc.creator.none.fl_str_mv Benzaquén, Tamara
Barrera Díaz, Deicy Amparo
Sapag, Karim
Alfano, Orlando
Eimer, Griselda Alejandra
author Benzaquén, Tamara
author_facet Benzaquén, Tamara
Barrera Díaz, Deicy Amparo
Sapag, Karim
Alfano, Orlando
Eimer, Griselda Alejandra
author_role author
author2 Barrera Díaz, Deicy Amparo
Sapag, Karim
Alfano, Orlando
Eimer, Griselda Alejandra
author2_role author
author
author
author
dc.subject.none.fl_str_mv Nano-structured catalysts
Heterogeneous photo-fenton process
Degradation of herbicides in aqueous phase.
topic Nano-structured catalysts
Heterogeneous photo-fenton process
Degradation of herbicides in aqueous phase.
dc.description.none.fl_txt_mv SBA-15 and KIT-6 materials have been synthesized and modified with iron salts by the wet impregnation method with different metal loadings. The different mesostructures obtained were characterized by N2 adsorption-desorption at 77 K, TPR and UVVIS-RD. These iron-containing mesostructured materials have been successfully tested for the heterogeneous photo-Fenton degradation of atrazine (ATZ) aqueous solutions using UV-visible irradiation at room temperature and close to neutral pH. Depending on the dispersion and size of the different iron species, the nanocomposites showed different catalytic behaviors. The results showed that the Fe/SBA-15(10) and Fe/KIT-6(5) catalysts exhibited the highest activities. Thus, the high performance of these materials indicates that the heterogeneous via of photo-Fenton process can also be efficiently employed to treat wastewaters containing pollutants such as herbicides, in order to reduce them to simpler and less toxic molecules.
Fil: Benzaquén, Tamara. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.
Fil: Barrera Díaz, Deicy Amparo. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.
Fil: Sapag, Karim. Universidad Nacional de San Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Aplicada: Dr. Jorge Andres Zgrablich. Laboratorio de Sólidos Porosos; Argentina.
Fil: Alfano, Orlando. Universidad Nacional del Litoral. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina.
Fil: Eimer, Griselda Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación y Tecnología Química; Argentina.
description SBA-15 and KIT-6 materials have been synthesized and modified with iron salts by the wet impregnation method with different metal loadings. The different mesostructures obtained were characterized by N2 adsorption-desorption at 77 K, TPR and UVVIS-RD. These iron-containing mesostructured materials have been successfully tested for the heterogeneous photo-Fenton degradation of atrazine (ATZ) aqueous solutions using UV-visible irradiation at room temperature and close to neutral pH. Depending on the dispersion and size of the different iron species, the nanocomposites showed different catalytic behaviors. The results showed that the Fe/SBA-15(10) and Fe/KIT-6(5) catalysts exhibited the highest activities. Thus, the high performance of these materials indicates that the heterogeneous via of photo-Fenton process can also be efficiently employed to treat wastewaters containing pollutants such as herbicides, in order to reduce them to simpler and less toxic molecules.
publishDate 2017
dc.date.none.fl_str_mv 2017
2022-05-27T18:07:04Z
2022-05-27T18:07:04Z
dc.type.none.fl_str_mv info:eu-repo/semantics/conferenceObject
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_5794
info:ar-repo/semantics/documentoDeConferencia
format conferenceObject
status_str publishedVersion
dc.identifier.none.fl_str_mv 3rd Iberoamerican Conference on Advanced Oxidation Technologies (2017).
http://hdl.handle.net/20.500.12272/6487
identifier_str_mv 3rd Iberoamerican Conference on Advanced Oxidation Technologies (2017).
url http://hdl.handle.net/20.500.12272/6487
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2022-05-27T18:07:04Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Eimer, Griselda Alejandra
No comercial. Sólo de uso académico.
eu_rights_str_mv openAccess
rights_invalid_str_mv 2022-05-27T18:07:04Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Eimer, Griselda Alejandra
No comercial. Sólo de uso académico.
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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