Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel
- Autores
- Maskavizan, Ana Justina; Quintana, Juan Pablo; Dalibón Bähler, Eugenia Laura; Márquez, Adriana Beatriz; Brühl, Sonia Patricia; Farina, Silvia Beatriz
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- documento de conferencia
- Estado
- versión aceptada
- Descripción
- CrN coatings deposited by Physical Vapor Deposition (PVD) are widely used due to their high hardness and high wear resistance, low friction coefficient and superior corrosion resistance. The latter makes this coating appropriate for protecting forming tools, moulds and components used in chemical processing. In this work, single layer CrN coatings were deposited on plasma nitrided and non treated AISI 4140 steel. The influence of nitriding on the wear resistance, coefficient of friction and corrosion resistance in acidic solutions and chloride solutions was studied. Thickness of the coatings was measured using optical microscopy, and surface hardness was assessed with a Vickers microindenter. Adhesion was determined using Rockwell indentation applying 150 kg and scratch test as well as Scratch test at different constant loads. Sliding wear resistance was studied with Pin-on-Disk tests under different normal loads and sliding distances, the coefficient of friction was registered during the tests and volume loss was calculated. Corrosion test were carried out using a 3.5 % NaCl solution and a 0.5 M H2SO4 solution as electrolytes. Nitrided steel without any coating was used also as comparison. Coating thickness was approximately (2.6 ± 0.4) μm and surface hardness reached a value of (1960 ± 160) HV0.05, being this a composed hardness because of the low film thickness. Adhesion was good for both substrates, non nitrided and nitrided steel, in both cases, it could be classified as HF1 according to VDI 3198 standard. In the case of the Scratch test, in the only coated samples, without nitriding as pre treatment the film cracking was observed at 50 N in the track, whereas in the duplex sample the coating had a better load bearing capacity and reached 70 N without damage. No delamination was detected around the scratch track in all cases. Wear volume loss was undetectable in the pin-on-disk test for the coated systems, whereas it was approximately 30 x 10-3 mm3 for the nitrided steel and 150 x 10-3 mm3 for the untreated steel. In the corrosion tests, the coating showed a passive behaviour as tested in NaCl solution and the corrosion current density was significantly lower for coated samples in the H2SO4 solution, proving that the CrN coating is suitable for protecting steel substrate in both chloride and acidic media.
Fil: Maskavizan, Ana Justina. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.
Fil: Quintana, Juan Pablo. Universidad Nacional de San Martín; Argentina.
Fil: Quintana, Juan Pablo. Comisión Nacional de Energía Atómica. Department of Materials; Argentina.
Fil: Dalibón Bähler, Eugenia Laura. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.
Fil: Farina, Silvia Beatriz. Comisión Nacional de Energía Atómica. Department of Materials; Argentina.
Fil: Farina, Silvia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
Fil: Farina, Silvia Beatriz. Universidad Nacional de San Martín; Argentina.
Fil: Márquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
Fil: Márquez, Adriana Beatriz. Universidad de Buenos Aires. Instituto de Física Interdisciplinaria y Aplicada; Argentina.
Fil: Brühl, Sonia Patricia. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.
Fil: Brühl, Sonia Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. - Materia
-
Plasma nitrided
AISI 4140
Physical vapor deposition
CrN coatings
Corrosion resistance - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- Attribution-NonCommercial-NoDerivatives 4.0 International
- Repositorio
.jpg)
- Institución
- Universidad Tecnológica Nacional
- OAI Identificador
- oai:ria.utn.edu.ar:20.500.12272/12309
Ver los metadatos del registro completo
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Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steelMaskavizan, Ana JustinaQuintana, Juan PabloDalibón Bähler, Eugenia LauraMárquez, Adriana BeatrizBrühl, Sonia PatriciaFarina, Silvia BeatrizPlasma nitridedAISI 4140Physical vapor depositionCrN coatingsCorrosion resistanceCrN coatings deposited by Physical Vapor Deposition (PVD) are widely used due to their high hardness and high wear resistance, low friction coefficient and superior corrosion resistance. The latter makes this coating appropriate for protecting forming tools, moulds and components used in chemical processing. In this work, single layer CrN coatings were deposited on plasma nitrided and non treated AISI 4140 steel. The influence of nitriding on the wear resistance, coefficient of friction and corrosion resistance in acidic solutions and chloride solutions was studied. Thickness of the coatings was measured using optical microscopy, and surface hardness was assessed with a Vickers microindenter. Adhesion was determined using Rockwell indentation applying 150 kg and scratch test as well as Scratch test at different constant loads. Sliding wear resistance was studied with Pin-on-Disk tests under different normal loads and sliding distances, the coefficient of friction was registered during the tests and volume loss was calculated. Corrosion test were carried out using a 3.5 % NaCl solution and a 0.5 M H2SO4 solution as electrolytes. Nitrided steel without any coating was used also as comparison. Coating thickness was approximately (2.6 ± 0.4) μm and surface hardness reached a value of (1960 ± 160) HV0.05, being this a composed hardness because of the low film thickness. Adhesion was good for both substrates, non nitrided and nitrided steel, in both cases, it could be classified as HF1 according to VDI 3198 standard. In the case of the Scratch test, in the only coated samples, without nitriding as pre treatment the film cracking was observed at 50 N in the track, whereas in the duplex sample the coating had a better load bearing capacity and reached 70 N without damage. No delamination was detected around the scratch track in all cases. Wear volume loss was undetectable in the pin-on-disk test for the coated systems, whereas it was approximately 30 x 10-3 mm3 for the nitrided steel and 150 x 10-3 mm3 for the untreated steel. In the corrosion tests, the coating showed a passive behaviour as tested in NaCl solution and the corrosion current density was significantly lower for coated samples in the H2SO4 solution, proving that the CrN coating is suitable for protecting steel substrate in both chloride and acidic media.Fil: Maskavizan, Ana Justina. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.Fil: Quintana, Juan Pablo. Universidad Nacional de San Martín; Argentina.Fil: Quintana, Juan Pablo. Comisión Nacional de Energía Atómica. Department of Materials; Argentina.Fil: Dalibón Bähler, Eugenia Laura. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.Fil: Farina, Silvia Beatriz. Comisión Nacional de Energía Atómica. Department of Materials; Argentina.Fil: Farina, Silvia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.Fil: Farina, Silvia Beatriz. Universidad Nacional de San Martín; Argentina.Fil: Márquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.Fil: Márquez, Adriana Beatriz. Universidad de Buenos Aires. Instituto de Física Interdisciplinaria y Aplicada; Argentina.Fil: Brühl, Sonia Patricia. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina.Fil: Brühl, Sonia Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.2025-03-06T15:59:14Z2024-05-24info:eu-repo/semantics/conferenceObjectinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_5794info:ar-repo/semantics/documentoDeConferenciapdfapplication/pdf50º International Conference on Metallurgical coatings and Thin Films, San Diego, USA (2024)https://icmctf2024.avs.org/http://hdl.handle.net/20.500.12272/12309enginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Maskavizan, Ana Justina ; Quintana, Juan Pablo ; Dalibón Bähler, Eugenia Laura ; Márquez, Adriana Beatriz ; Farina, Silvia Beatriz.No comercial con fines académicos. Licencia Creative Commons CC-BY-NC-SA.reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:44:54Zoai:ria.utn.edu.ar:20.500.12272/12309instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:44:54.879Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse |
| dc.title.none.fl_str_mv |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| title |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| spellingShingle |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel Maskavizan, Ana Justina Plasma nitrided AISI 4140 Physical vapor deposition CrN coatings Corrosion resistance |
| title_short |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| title_full |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| title_fullStr |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| title_full_unstemmed |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| title_sort |
Evaluation of wear and corrosion resistance in acidic and chloride solutions of PVD-CrN coatings on untreated and plasma nitrided AISI 4140 steel |
| dc.creator.none.fl_str_mv |
Maskavizan, Ana Justina Quintana, Juan Pablo Dalibón Bähler, Eugenia Laura Márquez, Adriana Beatriz Brühl, Sonia Patricia Farina, Silvia Beatriz |
| author |
Maskavizan, Ana Justina |
| author_facet |
Maskavizan, Ana Justina Quintana, Juan Pablo Dalibón Bähler, Eugenia Laura Márquez, Adriana Beatriz Brühl, Sonia Patricia Farina, Silvia Beatriz |
| author_role |
author |
| author2 |
Quintana, Juan Pablo Dalibón Bähler, Eugenia Laura Márquez, Adriana Beatriz Brühl, Sonia Patricia Farina, Silvia Beatriz |
| author2_role |
author author author author author |
| dc.subject.none.fl_str_mv |
Plasma nitrided AISI 4140 Physical vapor deposition CrN coatings Corrosion resistance |
| topic |
Plasma nitrided AISI 4140 Physical vapor deposition CrN coatings Corrosion resistance |
| dc.description.none.fl_txt_mv |
CrN coatings deposited by Physical Vapor Deposition (PVD) are widely used due to their high hardness and high wear resistance, low friction coefficient and superior corrosion resistance. The latter makes this coating appropriate for protecting forming tools, moulds and components used in chemical processing. In this work, single layer CrN coatings were deposited on plasma nitrided and non treated AISI 4140 steel. The influence of nitriding on the wear resistance, coefficient of friction and corrosion resistance in acidic solutions and chloride solutions was studied. Thickness of the coatings was measured using optical microscopy, and surface hardness was assessed with a Vickers microindenter. Adhesion was determined using Rockwell indentation applying 150 kg and scratch test as well as Scratch test at different constant loads. Sliding wear resistance was studied with Pin-on-Disk tests under different normal loads and sliding distances, the coefficient of friction was registered during the tests and volume loss was calculated. Corrosion test were carried out using a 3.5 % NaCl solution and a 0.5 M H2SO4 solution as electrolytes. Nitrided steel without any coating was used also as comparison. Coating thickness was approximately (2.6 ± 0.4) μm and surface hardness reached a value of (1960 ± 160) HV0.05, being this a composed hardness because of the low film thickness. Adhesion was good for both substrates, non nitrided and nitrided steel, in both cases, it could be classified as HF1 according to VDI 3198 standard. In the case of the Scratch test, in the only coated samples, without nitriding as pre treatment the film cracking was observed at 50 N in the track, whereas in the duplex sample the coating had a better load bearing capacity and reached 70 N without damage. No delamination was detected around the scratch track in all cases. Wear volume loss was undetectable in the pin-on-disk test for the coated systems, whereas it was approximately 30 x 10-3 mm3 for the nitrided steel and 150 x 10-3 mm3 for the untreated steel. In the corrosion tests, the coating showed a passive behaviour as tested in NaCl solution and the corrosion current density was significantly lower for coated samples in the H2SO4 solution, proving that the CrN coating is suitable for protecting steel substrate in both chloride and acidic media. Fil: Maskavizan, Ana Justina. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina. Fil: Quintana, Juan Pablo. Universidad Nacional de San Martín; Argentina. Fil: Quintana, Juan Pablo. Comisión Nacional de Energía Atómica. Department of Materials; Argentina. Fil: Dalibón Bähler, Eugenia Laura. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina. Fil: Farina, Silvia Beatriz. Comisión Nacional de Energía Atómica. Department of Materials; Argentina. Fil: Farina, Silvia Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Fil: Farina, Silvia Beatriz. Universidad Nacional de San Martín; Argentina. Fil: Márquez, Adriana Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Fil: Márquez, Adriana Beatriz. Universidad de Buenos Aires. Instituto de Física Interdisciplinaria y Aplicada; Argentina. Fil: Brühl, Sonia Patricia. Universidad Tecnológica Nacional. Facultad Regional Concepción del Uruguay. Departamento Ingeniería Electromecánica. Grupo de Ingeniería de Superficies; Argentina. Fil: Brühl, Sonia Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. |
| description |
CrN coatings deposited by Physical Vapor Deposition (PVD) are widely used due to their high hardness and high wear resistance, low friction coefficient and superior corrosion resistance. The latter makes this coating appropriate for protecting forming tools, moulds and components used in chemical processing. In this work, single layer CrN coatings were deposited on plasma nitrided and non treated AISI 4140 steel. The influence of nitriding on the wear resistance, coefficient of friction and corrosion resistance in acidic solutions and chloride solutions was studied. Thickness of the coatings was measured using optical microscopy, and surface hardness was assessed with a Vickers microindenter. Adhesion was determined using Rockwell indentation applying 150 kg and scratch test as well as Scratch test at different constant loads. Sliding wear resistance was studied with Pin-on-Disk tests under different normal loads and sliding distances, the coefficient of friction was registered during the tests and volume loss was calculated. Corrosion test were carried out using a 3.5 % NaCl solution and a 0.5 M H2SO4 solution as electrolytes. Nitrided steel without any coating was used also as comparison. Coating thickness was approximately (2.6 ± 0.4) μm and surface hardness reached a value of (1960 ± 160) HV0.05, being this a composed hardness because of the low film thickness. Adhesion was good for both substrates, non nitrided and nitrided steel, in both cases, it could be classified as HF1 according to VDI 3198 standard. In the case of the Scratch test, in the only coated samples, without nitriding as pre treatment the film cracking was observed at 50 N in the track, whereas in the duplex sample the coating had a better load bearing capacity and reached 70 N without damage. No delamination was detected around the scratch track in all cases. Wear volume loss was undetectable in the pin-on-disk test for the coated systems, whereas it was approximately 30 x 10-3 mm3 for the nitrided steel and 150 x 10-3 mm3 for the untreated steel. In the corrosion tests, the coating showed a passive behaviour as tested in NaCl solution and the corrosion current density was significantly lower for coated samples in the H2SO4 solution, proving that the CrN coating is suitable for protecting steel substrate in both chloride and acidic media. |
| publishDate |
2024 |
| dc.date.none.fl_str_mv |
2024-05-24 2025-03-06T15:59:14Z |
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info:eu-repo/semantics/conferenceObject info:eu-repo/semantics/acceptedVersion http://purl.org/coar/resource_type/c_5794 info:ar-repo/semantics/documentoDeConferencia |
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conferenceObject |
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acceptedVersion |
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50º International Conference on Metallurgical coatings and Thin Films, San Diego, USA (2024) https://icmctf2024.avs.org/ http://hdl.handle.net/20.500.12272/12309 |
| identifier_str_mv |
50º International Conference on Metallurgical coatings and Thin Films, San Diego, USA (2024) |
| url |
https://icmctf2024.avs.org/ http://hdl.handle.net/20.500.12272/12309 |
| dc.language.none.fl_str_mv |
eng |
| language |
eng |
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info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Maskavizan, Ana Justina ; Quintana, Juan Pablo ; Dalibón Bähler, Eugenia Laura ; Márquez, Adriana Beatriz ; Farina, Silvia Beatriz. No comercial con fines académicos. Licencia Creative Commons CC-BY-NC-SA. |
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openAccess |
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Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ Maskavizan, Ana Justina ; Quintana, Juan Pablo ; Dalibón Bähler, Eugenia Laura ; Márquez, Adriana Beatriz ; Farina, Silvia Beatriz. No comercial con fines académicos. Licencia Creative Commons CC-BY-NC-SA. |
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Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional |
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