Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings

Autores
Paola, Analía Cristina; Sathicq, Ángel Gabriel; Pérez, Miriam Cristina; Romanelli, Gustavo Pablo; Blustein, Guillermo
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Marine pollution in ports caused by biocides-based antifouling paints is a growing problem worldwide. In this paper we present a new sustainable alternative to reduce the use of copper and booster biocides in marine antifouling paints. In this way, five cinnamic acids and four alkyl-cinnamates were synthesized using ecoefficient procedures within the guidelines of sustainable chemistry. Experimental marine paints were formulated with these compounds and their antifouling performance was evaluated after 90 days of immersion in Mar del Plata harbor. Ecotoxicity-test on Artemia salina nauplii was also performed. Field and laboratory results indicate that 3,4,5-trimethoxycinnamic acid and isobutyl-cinnamate are promising additives for marine paints.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Facultad de Ciencias Naturales y Museo
Centro de Investigación y Desarrollo en Ciencias Aplicadas
Materia
Química
Cinnamic acids
Alkyl cinnamates
Antifouling paints
Green chemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
http://creativecommons.org/licenses/by-nc-nd/4.0/
Repositorio
SEDICI (UNLP)
Institución
Universidad Nacional de La Plata
OAI Identificador
oai:sedici.unlp.edu.ar:10915/189494
Acceder
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oai_identifier_str oai:sedici.unlp.edu.ar:10915/189494
network_acronym_str SEDICI
repository_id_str 1329
network_name_str SEDICI (UNLP)
spelling Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatingsPaola, Analía CristinaSathicq, Ángel GabrielPérez, Miriam CristinaRomanelli, Gustavo PabloBlustein, GuillermoQuímicaCinnamic acidsAlkyl cinnamatesAntifouling paintsGreen chemistryMarine pollution in ports caused by biocides-based antifouling paints is a growing problem worldwide. In this paper we present a new sustainable alternative to reduce the use of copper and booster biocides in marine antifouling paints. In this way, five cinnamic acids and four alkyl-cinnamates were synthesized using ecoefficient procedures within the guidelines of sustainable chemistry. Experimental marine paints were formulated with these compounds and their antifouling performance was evaluated after 90 days of immersion in Mar del Plata harbor. Ecotoxicity-test on Artemia salina nauplii was also performed. Field and laboratory results indicate that 3,4,5-trimethoxycinnamic acid and isobutyl-cinnamate are promising additives for marine paints.Centro de Investigación y Desarrollo en Tecnología de PinturasFacultad de Ciencias Naturales y MuseoCentro de Investigación y Desarrollo en Ciencias Aplicadas2025-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionArticulohttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfhttp://sedici.unlp.edu.ar/handle/10915/189494enginfo:eu-repo/semantics/altIdentifier/issn/2949-8392info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scenv.2025.100275info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)reponame:SEDICI (UNLP)instname:Universidad Nacional de La Platainstacron:UNLP2026-06-23T11:14:53Zoai:sedici.unlp.edu.ar:10915/189494Institucionalhttp://sedici.unlp.edu.ar/Universidad públicaNo correspondehttp://sedici.unlp.edu.ar/oai/snrdalira@sedici.unlp.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:13292026-06-23 11:14:54.049SEDICI (UNLP) - Universidad Nacional de La Platafalse
dc.title.none.fl_str_mv Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
title Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
spellingShingle Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
Paola, Analía Cristina
Química
Cinnamic acids
Alkyl cinnamates
Antifouling paints
Green chemistry
title_short Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
title_full Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
title_fullStr Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
title_full_unstemmed Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
title_sort Eco-efficient synthesis of cinnamic-compounds as antifouling additives for marine coatings
dc.creator.none.fl_str_mv Paola, Analía Cristina
Sathicq, Ángel Gabriel
Pérez, Miriam Cristina
Romanelli, Gustavo Pablo
Blustein, Guillermo
author Paola, Analía Cristina
author_facet Paola, Analía Cristina
Sathicq, Ángel Gabriel
Pérez, Miriam Cristina
Romanelli, Gustavo Pablo
Blustein, Guillermo
author_role author
author2 Sathicq, Ángel Gabriel
Pérez, Miriam Cristina
Romanelli, Gustavo Pablo
Blustein, Guillermo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Química
Cinnamic acids
Alkyl cinnamates
Antifouling paints
Green chemistry
topic Química
Cinnamic acids
Alkyl cinnamates
Antifouling paints
Green chemistry
dc.description.none.fl_txt_mv Marine pollution in ports caused by biocides-based antifouling paints is a growing problem worldwide. In this paper we present a new sustainable alternative to reduce the use of copper and booster biocides in marine antifouling paints. In this way, five cinnamic acids and four alkyl-cinnamates were synthesized using ecoefficient procedures within the guidelines of sustainable chemistry. Experimental marine paints were formulated with these compounds and their antifouling performance was evaluated after 90 days of immersion in Mar del Plata harbor. Ecotoxicity-test on Artemia salina nauplii was also performed. Field and laboratory results indicate that 3,4,5-trimethoxycinnamic acid and isobutyl-cinnamate are promising additives for marine paints.
Centro de Investigación y Desarrollo en Tecnología de Pinturas
Facultad de Ciencias Naturales y Museo
Centro de Investigación y Desarrollo en Ciencias Aplicadas
description Marine pollution in ports caused by biocides-based antifouling paints is a growing problem worldwide. In this paper we present a new sustainable alternative to reduce the use of copper and booster biocides in marine antifouling paints. In this way, five cinnamic acids and four alkyl-cinnamates were synthesized using ecoefficient procedures within the guidelines of sustainable chemistry. Experimental marine paints were formulated with these compounds and their antifouling performance was evaluated after 90 days of immersion in Mar del Plata harbor. Ecotoxicity-test on Artemia salina nauplii was also performed. Field and laboratory results indicate that 3,4,5-trimethoxycinnamic acid and isobutyl-cinnamate are promising additives for marine paints.
publishDate 2025
dc.date.none.fl_str_mv 2025-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
Articulo
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://sedici.unlp.edu.ar/handle/10915/189494
url http://sedici.unlp.edu.ar/handle/10915/189494
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/issn/2949-8392
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scenv.2025.100275
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:SEDICI (UNLP)
instname:Universidad Nacional de La Plata
instacron:UNLP
reponame_str SEDICI (UNLP)
collection SEDICI (UNLP)
instname_str Universidad Nacional de La Plata
instacron_str UNLP
institution UNLP
repository.name.fl_str_mv SEDICI (UNLP) - Universidad Nacional de La Plata
repository.mail.fl_str_mv alira@sedici.unlp.edu.ar
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