Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage

Autores
Juárez, Juliana María; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work is to prepare CMK-1 modified with Zn and Ni in order to improve its capacity in hydrogen stor- age. The approach that we have followed includes synthesis of nanostructures with the experimental study of its ad- sorption capacity and storage properties. We have shown that CMK-1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron micro- scope, transmission electron microscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK 1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK-1 does not increase hydrogen storage capacity at low pres- sure. However, at a higher pressure (10 bars), Ni-CMK-1 displays improved results in hydrogen uptake compared with those of CMK-1 pristine, 2.4 and 2.1 wt.%, respectively.. Copyright © 2015 John Wiley & Sons, Ltd.
Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
Fuente
INTERNATIONAL JOURNAL OF ENERGY RESEARCH Int. J. Energy Res. 39:941–953 (2015).
Materia
CMK-1
Zn-CMK-1
Ni-CMK-1
Hydrogen
Storage
Composite
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Attribution-NonCommercial-NoDerivatives 4.0 International
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/14055
Acceder
id RIAUTN_34b88ce0ae335beeb20c689d16e73cbd
oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/14055
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storageJuárez, Juliana MaríaGómez Costa, Marcos BrunoAnunziata, Oscar AlfredoCMK-1Zn-CMK-1Ni-CMK-1HydrogenStorageCompositeThe aim of this work is to prepare CMK-1 modified with Zn and Ni in order to improve its capacity in hydrogen stor- age. The approach that we have followed includes synthesis of nanostructures with the experimental study of its ad- sorption capacity and storage properties. We have shown that CMK-1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron micro- scope, transmission electron microscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK 1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK-1 does not increase hydrogen storage capacity at low pres- sure. However, at a higher pressure (10 bars), Ni-CMK-1 displays improved results in hydrogen uptake compared with those of CMK-1 pristine, 2.4 and 2.1 wt.%, respectively.. Copyright © 2015 John Wiley & Sons, Ltd.Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Peer ReviewedWiley Online Library2025-10-27T18:49:46Z2015info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfInternational Journal of Energy Researchhttps://hdl.handle.net/20.500.12272/14055https://doi.org/10.1002/er.3298INTERNATIONAL JOURNAL OF ENERGY RESEARCH Int. J. Energy Res. 39:941–953 (2015).reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacionalenginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Juárez, Juliana María; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo.https://creativecommons.org/licenses/by-nc-nd/4.0/2026-09-24T12:44:49Zoai:ria.utn.edu.ar:20.500.12272/14055instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:44:51.238Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
spellingShingle Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
Juárez, Juliana María
CMK-1
Zn-CMK-1
Ni-CMK-1
Hydrogen
Storage
Composite
title_short Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_full Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_fullStr Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_full_unstemmed Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
title_sort Preparation and characterization of activated CMK-1 with Zn and Ni species applied in hydrogen storage
dc.creator.none.fl_str_mv Juárez, Juliana María
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author Juárez, Juliana María
author_facet Juárez, Juliana María
Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author_role author
author2 Gómez Costa, Marcos Bruno
Anunziata, Oscar Alfredo
author2_role author
author
dc.subject.none.fl_str_mv CMK-1
Zn-CMK-1
Ni-CMK-1
Hydrogen
Storage
Composite
topic CMK-1
Zn-CMK-1
Ni-CMK-1
Hydrogen
Storage
Composite
dc.description.none.fl_txt_mv The aim of this work is to prepare CMK-1 modified with Zn and Ni in order to improve its capacity in hydrogen stor- age. The approach that we have followed includes synthesis of nanostructures with the experimental study of its ad- sorption capacity and storage properties. We have shown that CMK-1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron micro- scope, transmission electron microscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK 1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK-1 does not increase hydrogen storage capacity at low pres- sure. However, at a higher pressure (10 bars), Ni-CMK-1 displays improved results in hydrogen uptake compared with those of CMK-1 pristine, 2.4 and 2.1 wt.%, respectively.. Copyright © 2015 John Wiley & Sons, Ltd.
Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
description The aim of this work is to prepare CMK-1 modified with Zn and Ni in order to improve its capacity in hydrogen stor- age. The approach that we have followed includes synthesis of nanostructures with the experimental study of its ad- sorption capacity and storage properties. We have shown that CMK-1 ordered porous carbon modified with metals is a promising material for hydrogen storage. The incorporation of metals was performed by wetness impregnation. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron micro- scope, transmission electron microscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller methods. The CMK 1 modified with Zn showed the highest H2 uptake at 77 K and at low and high pressure (1.5 and 4.4 wt.% at 1 and 10 bar, respectively). The introduction of Ni into CMK-1 does not increase hydrogen storage capacity at low pres- sure. However, at a higher pressure (10 bars), Ni-CMK-1 displays improved results in hydrogen uptake compared with those of CMK-1 pristine, 2.4 and 2.1 wt.%, respectively.. Copyright © 2015 John Wiley & Sons, Ltd.
publishDate 2015
dc.date.none.fl_str_mv 2015
2025-10-27T18:49:46Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv International Journal of Energy Research
https://hdl.handle.net/20.500.12272/14055
https://doi.org/10.1002/er.3298
identifier_str_mv International Journal of Energy Research
url https://hdl.handle.net/20.500.12272/14055
https://doi.org/10.1002/er.3298
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juárez, Juliana María; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo.
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juárez, Juliana María; Gómez Costa, Marcos Bruno; Anunziata, Oscar Alfredo.
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley Online Library
publisher.none.fl_str_mv Wiley Online Library
dc.source.none.fl_str_mv INTERNATIONAL JOURNAL OF ENERGY RESEARCH Int. J. Energy Res. 39:941–953 (2015).
reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
_version_ 1877230888517894144
score 13.24418

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