Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage

Autores
Juárez, Juliana; Gómez Costa, Marcos; Cussa, Jorgelina; Anunziata, Oscar
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this work is to synthesize a nanostructured Carbon CMK-3 modified with V in order to increase its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. Ordered nanoporous carbon CMK-3 was synthesized via a two-step impregnation of the SBA-15 mesopores with a solution of sucrose using an incipient wetness method. The sucrose–silica composite was heated at 1173 K for 4 h under nitrogen flow. The silica template was dissolved with 5 wt% hydrofluoric acid in order to remove the silica. The template-free carbon product thus obtained was filtered, washed with deionized water and ethanol, and dried. [1] V-CMK-3 was prepared by wetness impregnation using VCl3 as source of Vanadium in order to increase the amount of hydrogen adsorbed. The sample of V-CMK-3 was treated under H2 flow two times at 1173 K. Porous carbon CMK-3 and the sample modified with V were characterized by XRD, FTIR, XPS, BET, TEM and SEM. These studies indicate that it was possible to obtain a CMK-3 replica successfully from SBA-15, using sucrose as a carbon precursor. [2] The surface areas are 1320 m2/g and 1050 m2/g for CMK-3 and V-CMK-3, respectively. While the nanomaterial area is significantly smaller with the incorporation of the metal, CMK-3`s characteristic structure is maintained after the metal is within the host, in agreement with the XRD studies. Measurements of hydrogen adsorption at cryogenic temperatures and low pressures were performed. The nanoparticles of V incorporated onto the nanostructured carbon CMK-3 showed higher hydrogen uptake at low and high pressures than CMK-3. (3.4 wt% and 2.2 wt% respectively of H2 sorption at 10 bar and 77 K).
Fil: Juárez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
Materia
CMK-3
V-CMK-3
hydrogen
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Attribution-NonCommercial-NoDerivatives 4.0 International
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/14304
Acceder
id RIAUTN_a011c1474c2d40889745e94db59c6508
oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/14304
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storageJuárez, JulianaGómez Costa, MarcosCussa, JorgelinaAnunziata, OscarCMK-3V-CMK-3hydrogenThe aim of this work is to synthesize a nanostructured Carbon CMK-3 modified with V in order to increase its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. Ordered nanoporous carbon CMK-3 was synthesized via a two-step impregnation of the SBA-15 mesopores with a solution of sucrose using an incipient wetness method. The sucrose–silica composite was heated at 1173 K for 4 h under nitrogen flow. The silica template was dissolved with 5 wt% hydrofluoric acid in order to remove the silica. The template-free carbon product thus obtained was filtered, washed with deionized water and ethanol, and dried. [1] V-CMK-3 was prepared by wetness impregnation using VCl3 as source of Vanadium in order to increase the amount of hydrogen adsorbed. The sample of V-CMK-3 was treated under H2 flow two times at 1173 K. Porous carbon CMK-3 and the sample modified with V were characterized by XRD, FTIR, XPS, BET, TEM and SEM. These studies indicate that it was possible to obtain a CMK-3 replica successfully from SBA-15, using sucrose as a carbon precursor. [2] The surface areas are 1320 m2/g and 1050 m2/g for CMK-3 and V-CMK-3, respectively. While the nanomaterial area is significantly smaller with the incorporation of the metal, CMK-3`s characteristic structure is maintained after the metal is within the host, in agreement with the XRD studies. Measurements of hydrogen adsorption at cryogenic temperatures and low pressures were performed. The nanoparticles of V incorporated onto the nanostructured carbon CMK-3 showed higher hydrogen uptake at low and high pressures than CMK-3. (3.4 wt% and 2.2 wt% respectively of H2 sorption at 10 bar and 77 K).Fil: Juárez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Gómez Costa, Marcos. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Fil: Anunziata, Oscar. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.Peer ReviewedXXIII INTERNATIONAL MATERIALS RESEARCH CONGRESS2025-12-04T13:57:20Z2014info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttps://hdl.handle.net/20.500.12272/14304enginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Juliana Juárez2014reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-10-01T11:58:44Zoai:ria.utn.edu.ar:20.500.12272/14304instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-10-01 11:58:45.301Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
title Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
spellingShingle Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
Juárez, Juliana
CMK-3
V-CMK-3
hydrogen
title_short Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
title_full Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
title_fullStr Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
title_full_unstemmed Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
title_sort Preparation and characterization of activated CMK-3 modified with vanadium applied in hydrogen storage
dc.creator.none.fl_str_mv Juárez, Juliana
Gómez Costa, Marcos
Cussa, Jorgelina
Anunziata, Oscar
author Juárez, Juliana
author_facet Juárez, Juliana
Gómez Costa, Marcos
Cussa, Jorgelina
Anunziata, Oscar
author_role author
author2 Gómez Costa, Marcos
Cussa, Jorgelina
Anunziata, Oscar
author2_role author
author
author
dc.subject.none.fl_str_mv CMK-3
V-CMK-3
hydrogen
topic CMK-3
V-CMK-3
hydrogen
dc.description.none.fl_txt_mv The aim of this work is to synthesize a nanostructured Carbon CMK-3 modified with V in order to increase its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. Ordered nanoporous carbon CMK-3 was synthesized via a two-step impregnation of the SBA-15 mesopores with a solution of sucrose using an incipient wetness method. The sucrose–silica composite was heated at 1173 K for 4 h under nitrogen flow. The silica template was dissolved with 5 wt% hydrofluoric acid in order to remove the silica. The template-free carbon product thus obtained was filtered, washed with deionized water and ethanol, and dried. [1] V-CMK-3 was prepared by wetness impregnation using VCl3 as source of Vanadium in order to increase the amount of hydrogen adsorbed. The sample of V-CMK-3 was treated under H2 flow two times at 1173 K. Porous carbon CMK-3 and the sample modified with V were characterized by XRD, FTIR, XPS, BET, TEM and SEM. These studies indicate that it was possible to obtain a CMK-3 replica successfully from SBA-15, using sucrose as a carbon precursor. [2] The surface areas are 1320 m2/g and 1050 m2/g for CMK-3 and V-CMK-3, respectively. While the nanomaterial area is significantly smaller with the incorporation of the metal, CMK-3`s characteristic structure is maintained after the metal is within the host, in agreement with the XRD studies. Measurements of hydrogen adsorption at cryogenic temperatures and low pressures were performed. The nanoparticles of V incorporated onto the nanostructured carbon CMK-3 showed higher hydrogen uptake at low and high pressures than CMK-3. (3.4 wt% and 2.2 wt% respectively of H2 sorption at 10 bar and 77 K).
Fil: Juárez, Juliana. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Cussa, Jorgelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
description The aim of this work is to synthesize a nanostructured Carbon CMK-3 modified with V in order to increase its capacity in hydrogen storage. The approach that we have followed includes synthesis of nanostructures with the experimental study of its adsorption capacity and storage properties. Ordered nanoporous carbon CMK-3 was synthesized via a two-step impregnation of the SBA-15 mesopores with a solution of sucrose using an incipient wetness method. The sucrose–silica composite was heated at 1173 K for 4 h under nitrogen flow. The silica template was dissolved with 5 wt% hydrofluoric acid in order to remove the silica. The template-free carbon product thus obtained was filtered, washed with deionized water and ethanol, and dried. [1] V-CMK-3 was prepared by wetness impregnation using VCl3 as source of Vanadium in order to increase the amount of hydrogen adsorbed. The sample of V-CMK-3 was treated under H2 flow two times at 1173 K. Porous carbon CMK-3 and the sample modified with V were characterized by XRD, FTIR, XPS, BET, TEM and SEM. These studies indicate that it was possible to obtain a CMK-3 replica successfully from SBA-15, using sucrose as a carbon precursor. [2] The surface areas are 1320 m2/g and 1050 m2/g for CMK-3 and V-CMK-3, respectively. While the nanomaterial area is significantly smaller with the incorporation of the metal, CMK-3`s characteristic structure is maintained after the metal is within the host, in agreement with the XRD studies. Measurements of hydrogen adsorption at cryogenic temperatures and low pressures were performed. The nanoparticles of V incorporated onto the nanostructured carbon CMK-3 showed higher hydrogen uptake at low and high pressures than CMK-3. (3.4 wt% and 2.2 wt% respectively of H2 sorption at 10 bar and 77 K).
publishDate 2014
dc.date.none.fl_str_mv 2014
2025-12-04T13:57:20Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.12272/14304
url https://hdl.handle.net/20.500.12272/14304
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juliana Juárez
2014
eu_rights_str_mv openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juliana Juárez
2014
dc.format.none.fl_str_mv pdf
application/pdf
dc.publisher.none.fl_str_mv XXIII INTERNATIONAL MATERIALS RESEARCH CONGRESS
publisher.none.fl_str_mv XXIII INTERNATIONAL MATERIALS RESEARCH CONGRESS
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
_version_ 1877862399866830848
score 13.364332

Publicaciones similares