Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage

Autores
Juárez, Juliana María; Cussa, Jogelina; Anunziata, Oscar Alfredo; Gómez Costa, Marcos Bruno
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión borrador
Descripción
In this work, we report the synthesis and characterization of iron oxide nanoparticles supported in nanostructured carbon (CMK-3). This material is promising in the application of hydrogen adsorption for energy storage. The material with iron oxide nano- particles (Fe-CMK-3) was successfully synthesized and characterized by X-ray diffraction, textural properties analysis, transmission and scanning electron microsco- py, X-ray photoelectron spectroscopy, and magnetiza- tion studies. A large amount of the iron incorporated as iron oxide nanoparticles was in the magnetite phase. The incorporation of magnetite on the CMK-3 carbon surface significantly improved the storage capacity of hydrogen (4.45 wt% at 77 K and 10 bar) compared with the CMK-3 framework alone (2.20 wt% at 77 K and 10 bar). The synthesized material is promising for hy- drogen adsorption by weak bond forces (physisorption). A hydrogen adsorption mechanism was proposed in which the nanoparticles of magnetite have an important role.
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Cussa, Jogelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
Materia
Magnetite
CMK-3
Hydrogen
Storage
Adsorption
Nanocomposites
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2024-04-18T22:21:49Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/10593
Acceder
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oai_identifier_str oai:ria.utn.edu.ar:20.500.12272/10593
network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storageJuárez, Juliana MaríaCussa, JogelinaAnunziata, Oscar AlfredoGómez Costa, Marcos BrunoMagnetiteCMK-3HydrogenStorageAdsorptionNanocompositesIn this work, we report the synthesis and characterization of iron oxide nanoparticles supported in nanostructured carbon (CMK-3). This material is promising in the application of hydrogen adsorption for energy storage. The material with iron oxide nano- particles (Fe-CMK-3) was successfully synthesized and characterized by X-ray diffraction, textural properties analysis, transmission and scanning electron microsco- py, X-ray photoelectron spectroscopy, and magnetiza- tion studies. A large amount of the iron incorporated as iron oxide nanoparticles was in the magnetite phase. The incorporation of magnetite on the CMK-3 carbon surface significantly improved the storage capacity of hydrogen (4.45 wt% at 77 K and 10 bar) compared with the CMK-3 framework alone (2.20 wt% at 77 K and 10 bar). The synthesized material is promising for hy- drogen adsorption by weak bond forces (physisorption). A hydrogen adsorption mechanism was proposed in which the nanoparticles of magnetite have an important role.Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Cussa, Jogelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Peer Reviewed2024-04-18T22:21:49Z2024-04-18T22:21:49Z2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttp://hdl.handle.net/20.500.12272/10593-enginfo:eu-repo/semantics/openAccess2024-04-18T22:21:49Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalJuárez, Juliana M.https://creativecommons.org/licenses/by-nc-sa/4.0/reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:46:59Zoai:ria.utn.edu.ar:20.500.12272/10593instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:47:01.769Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
title Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
spellingShingle Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
Juárez, Juliana María
Magnetite
CMK-3
Hydrogen
Storage
Adsorption
Nanocomposites
title_short Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
title_full Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
title_fullStr Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
title_full_unstemmed Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
title_sort Synthesis and characteristics of CMK-3 modified with magnetite nanoparticles for application in hydrogen storage
dc.creator.none.fl_str_mv Juárez, Juliana María
Cussa, Jogelina
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
author Juárez, Juliana María
author_facet Juárez, Juliana María
Cussa, Jogelina
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
author_role author
author2 Cussa, Jogelina
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
author2_role author
author
author
dc.subject.none.fl_str_mv Magnetite
CMK-3
Hydrogen
Storage
Adsorption
Nanocomposites
topic Magnetite
CMK-3
Hydrogen
Storage
Adsorption
Nanocomposites
dc.description.none.fl_txt_mv In this work, we report the synthesis and characterization of iron oxide nanoparticles supported in nanostructured carbon (CMK-3). This material is promising in the application of hydrogen adsorption for energy storage. The material with iron oxide nano- particles (Fe-CMK-3) was successfully synthesized and characterized by X-ray diffraction, textural properties analysis, transmission and scanning electron microsco- py, X-ray photoelectron spectroscopy, and magnetiza- tion studies. A large amount of the iron incorporated as iron oxide nanoparticles was in the magnetite phase. The incorporation of magnetite on the CMK-3 carbon surface significantly improved the storage capacity of hydrogen (4.45 wt% at 77 K and 10 bar) compared with the CMK-3 framework alone (2.20 wt% at 77 K and 10 bar). The synthesized material is promising for hy- drogen adsorption by weak bond forces (physisorption). A hydrogen adsorption mechanism was proposed in which the nanoparticles of magnetite have an important role.
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Cussa, Jogelina. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
description In this work, we report the synthesis and characterization of iron oxide nanoparticles supported in nanostructured carbon (CMK-3). This material is promising in the application of hydrogen adsorption for energy storage. The material with iron oxide nano- particles (Fe-CMK-3) was successfully synthesized and characterized by X-ray diffraction, textural properties analysis, transmission and scanning electron microsco- py, X-ray photoelectron spectroscopy, and magnetiza- tion studies. A large amount of the iron incorporated as iron oxide nanoparticles was in the magnetite phase. The incorporation of magnetite on the CMK-3 carbon surface significantly improved the storage capacity of hydrogen (4.45 wt% at 77 K and 10 bar) compared with the CMK-3 framework alone (2.20 wt% at 77 K and 10 bar). The synthesized material is promising for hy- drogen adsorption by weak bond forces (physisorption). A hydrogen adsorption mechanism was proposed in which the nanoparticles of magnetite have an important role.
publishDate 2022
dc.date.none.fl_str_mv 2022
2024-04-18T22:21:49Z
2024-04-18T22:21:49Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/draft
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str draft
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/10593
-
url http://hdl.handle.net/20.500.12272/10593
identifier_str_mv -
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2024-04-18T22:21:49Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv 2024-04-18T22:21:49Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.24418

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