Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste

Autores
Juárez, Juliana María; Ledesma, Brenda Cecilia; Anunziata, Oscar Alfredo; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión borrador
Descripción
The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470 , 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m /g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 C and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
Materia
orange peel waste
carbonaceous nanomaterials
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2024-04-25T23:29:52Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/10666
Acceder
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network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels wasteJuárez, Juliana MaríaLedesma, Brenda CeciliaAnunziata, Oscar AlfredoGómez Costa, Marcos BrunoBeltramone, Andrea Raquelorange peel wastecarbonaceous nanomaterialsThe recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470 , 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m /g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 C and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Peer Reviewed2024-04-25T23:29:52Z2024-04-25T23:29:52Z2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/drafthttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttp://hdl.handle.net/20.500.12272/10666-enginfo:eu-repo/semantics/openAccess2024-04-25T23:29:52Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalJuárez, Juliana M.https://creativecommons.org/licenses/by-nc-sa/4.0/reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-10-01T12:00:56Zoai:ria.utn.edu.ar:20.500.12272/10666instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-10-01 12:00:56.563Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
title Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
spellingShingle Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
Juárez, Juliana María
orange peel waste
carbonaceous nanomaterials
title_short Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
title_full Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
title_fullStr Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
title_full_unstemmed Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
title_sort Synthesis, characterization and hydrogen storage application of an activated carbon derivated from orange peels waste
dc.creator.none.fl_str_mv Juárez, Juliana María
Ledesma, Brenda Cecilia
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author Juárez, Juliana María
author_facet Juárez, Juliana María
Ledesma, Brenda Cecilia
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author_role author
author2 Ledesma, Brenda Cecilia
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author2_role author
author
author
author
dc.subject.none.fl_str_mv orange peel waste
carbonaceous nanomaterials
topic orange peel waste
carbonaceous nanomaterials
dc.description.none.fl_txt_mv The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470 , 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m /g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 C and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
description The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470 , 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m /g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 C and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
publishDate 2022
dc.date.none.fl_str_mv 2022
2024-04-25T23:29:52Z
2024-04-25T23:29:52Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/draft
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str draft
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/10666
-
url http://hdl.handle.net/20.500.12272/10666
identifier_str_mv -
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2024-04-25T23:29:52Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv 2024-04-25T23:29:52Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.365483

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