Orange peel biowaste used as a nanoscopic hydrogen reservoir

Autores
Juárez, Juliana María; Ledesma, Brenda; Anunziata, Oscar Alfredo; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work addresses the bio-waste vaporization approach for the development of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. In this research, activated carbons were synthesized from orange peel using different synthesis conditions. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the acid concentration, the substrate / activating agent ratio, and the contact time between them. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, a phosphoric acid concentration of 50% by weight and a BET area of 1402 m2 / g. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 oC and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
Materia
orange peel
biowaste vaporization
carbonaceous nanomaterials
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2024-04-25T22:49:57Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/10665
Acceder
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network_acronym_str RIAUTN
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network_name_str Repositorio Institucional Abierto (UTN)
spelling Orange peel biowaste used as a nanoscopic hydrogen reservoirJuárez, Juliana MaríaLedesma, BrendaAnunziata, Oscar AlfredoGómez Costa, Marcos BrunoBeltramone, Andrea Raquelorange peelbiowaste vaporizationcarbonaceous nanomaterialsThis work addresses the bio-waste vaporization approach for the development of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. In this research, activated carbons were synthesized from orange peel using different synthesis conditions. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the acid concentration, the substrate / activating agent ratio, and the contact time between them. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, a phosphoric acid concentration of 50% by weight and a BET area of 1402 m2 / g. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 oC and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Peer Reviewed2024-04-25T22:49:57Z2024-04-25T22:49:57Z2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttp://hdl.handle.net/20.500.12272/10665-engenginfo:eu-repo/semantics/openAccess2024-04-25T22:49:57Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalJuárez, Juliana M.https://creativecommons.org/licenses/by-nc-sa/4.0/reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:44:32Zoai:ria.utn.edu.ar:20.500.12272/10665instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:44:32.509Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Orange peel biowaste used as a nanoscopic hydrogen reservoir
title Orange peel biowaste used as a nanoscopic hydrogen reservoir
spellingShingle Orange peel biowaste used as a nanoscopic hydrogen reservoir
Juárez, Juliana María
orange peel
biowaste vaporization
carbonaceous nanomaterials
title_short Orange peel biowaste used as a nanoscopic hydrogen reservoir
title_full Orange peel biowaste used as a nanoscopic hydrogen reservoir
title_fullStr Orange peel biowaste used as a nanoscopic hydrogen reservoir
title_full_unstemmed Orange peel biowaste used as a nanoscopic hydrogen reservoir
title_sort Orange peel biowaste used as a nanoscopic hydrogen reservoir
dc.creator.none.fl_str_mv Juárez, Juliana María
Ledesma, Brenda
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author Juárez, Juliana María
author_facet Juárez, Juliana María
Ledesma, Brenda
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author_role author
author2 Ledesma, Brenda
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
author2_role author
author
author
author
dc.subject.none.fl_str_mv orange peel
biowaste vaporization
carbonaceous nanomaterials
topic orange peel
biowaste vaporization
carbonaceous nanomaterials
dc.description.none.fl_txt_mv This work addresses the bio-waste vaporization approach for the development of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. In this research, activated carbons were synthesized from orange peel using different synthesis conditions. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the acid concentration, the substrate / activating agent ratio, and the contact time between them. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, a phosphoric acid concentration of 50% by weight and a BET area of 1402 m2 / g. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 oC and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea Raquel. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
description This work addresses the bio-waste vaporization approach for the development of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. In this research, activated carbons were synthesized from orange peel using different synthesis conditions. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the acid concentration, the substrate / activating agent ratio, and the contact time between them. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, a phosphoric acid concentration of 50% by weight and a BET area of 1402 m2 / g. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196,15 oC and 10 bar). The synthesized material shows promise in absorbing hydrogen by weak binding forces (physisorption).
publishDate 2022
dc.date.none.fl_str_mv 2022
2024-04-25T22:49:57Z
2024-04-25T22:49:57Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/10665
-
url http://hdl.handle.net/20.500.12272/10665
identifier_str_mv -
dc.language.none.fl_str_mv eng
eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2024-04-25T22:49:57Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv 2024-04-25T22:49:57Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Juárez, Juliana M.
https://creativecommons.org/licenses/by-nc-sa/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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score 13.24418

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