Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application

Autores
Juárez, Juliana María; Anunziata, Oscar Alfredo; Gómez Costa, Marcos Bruno; Beltramone, Andrea Raquel; Ledesma, Brenda Cecilia
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m2/g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196oC and 10 bar). The synthesized material shows promise in adsorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
Materia
orange peel waste
circular economy
carbonaceous nanomaterials
Nivel de accesibilidad
acceso abierto
Condiciones de uso
2024-04-15T22:54:01Z
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/10525
Acceder
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network_acronym_str RIAUTN
repository_id_str a
network_name_str Repositorio Institucional Abierto (UTN)
spelling Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage applicationJuárez, Juliana MaríaAnunziata, Oscar AlfredoGómez Costa, Marcos BrunoBeltramone, Andrea RaquelLedesma, Brenda Ceciliaorange peel wastecircular economycarbonaceous nanomaterialsThe recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m2/g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196oC and 10 bar). The synthesized material shows promise in adsorbing hydrogen by weak binding forces (physisorption).Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.Peer Reviewed2024-04-15T22:54:01Z2024-04-15T22:54:01Z2022info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfhttp://hdl.handle.net/20.500.12272/10525-enginfo:eu-repo/semantics/openAccess2024-04-15T22:54:01Zhttp://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 InternacionalBeltramone, Andrea Raquelhttps://creativecommons.org/licenses/by-nc-sa/4.0/reponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:46:23Zoai:ria.utn.edu.ar:20.500.12272/10525instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:46:24.521Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
title Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
spellingShingle Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
Juárez, Juliana María
orange peel waste
circular economy
carbonaceous nanomaterials
title_short Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
title_full Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
title_fullStr Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
title_full_unstemmed Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
title_sort Sustainable utilization of orange peels waste for preparation of activated carbon: synthesis, characterization and hydrogen storage application
dc.creator.none.fl_str_mv Juárez, Juliana María
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
Ledesma, Brenda Cecilia
author Juárez, Juliana María
author_facet Juárez, Juliana María
Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
Ledesma, Brenda Cecilia
author_role author
author2 Anunziata, Oscar Alfredo
Gómez Costa, Marcos Bruno
Beltramone, Andrea Raquel
Ledesma, Brenda Cecilia
author2_role author
author
author
author
dc.subject.none.fl_str_mv orange peel waste
circular economy
carbonaceous nanomaterials
topic orange peel waste
circular economy
carbonaceous nanomaterials
dc.description.none.fl_txt_mv The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m2/g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196oC and 10 bar). The synthesized material shows promise in adsorbing hydrogen by weak binding forces (physisorption).
Fil: Juárez, Juliana M.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Ledesma, Brenda Cecilia. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Anunziata, Oscar A.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Gómez Costa, Marcos B.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Fil: Beltramone, Andrea R.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología. Córdoba; Argentina.
Peer Reviewed
description The recovery and reuse of orange peel waste (OP) is a sustainable strategy in a circular economy. In this research, OP was used as the raw material for the preparation of a novel carbonaceous nanomaterial to be used in the adsorption of hydrogen as an alternative in the use of green hydrogen. Activated carbons were synthesized from orange peel using different synthesis conditions. The activation of the carbon was carried out by means of a chemical process with phosphoric acid as activating agent, varying the the activating agent/precursor ratio, and the contact time between them. The activating agent used is a solution of phosphoric acid (50 wt %) in different weight ratios of acid/precursor of 3:1 or 6:1, with resting time of 24 hours. The best support was obtained using a carbonization time of 1 h, a carbonization temperature of 470oC, 6:1 precursor/acid ratio and 24 hours of resting time. According XRD analysis all samples present amorphous structure of activated carbons with BET surface areas of 1000 to 1400 m2/g. With the activated carbons obtained with the best structure and texture, the adsorption of hydrogen and the effects on their meso / microporosity were studied. Said material significantly improved H2 storage behaviour compared to CMK-3 type nanostructured carbon (3.1% by weight at -196oC and 10 bar). The synthesized material shows promise in adsorbing hydrogen by weak binding forces (physisorption).
publishDate 2022
dc.date.none.fl_str_mv 2022
2024-04-15T22:54:01Z
2024-04-15T22:54:01Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.12272/10525
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url http://hdl.handle.net/20.500.12272/10525
identifier_str_mv -
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
2024-04-15T22:54:01Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Beltramone, Andrea Raquel
https://creativecommons.org/licenses/by-nc-sa/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv 2024-04-15T22:54:01Z
http://creativecommons.org/licenses/by-nc-nd/4.0/
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Beltramone, Andrea Raquel
https://creativecommons.org/licenses/by-nc-sa/4.0/
dc.format.none.fl_str_mv pdf
application/pdf
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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