Hydrogen storage on a novel nanostructured carbon material modified with zirconia

Autores
Juárez , Juliana María; Venosta, Lisandro F; Anunziata , Oscar Alfredo; Gómez Costa, Marcos Bruno
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
In this work, we report the synthesis and characterization of zirconium oxide supported in nanostructured carbon material synthesized by a new direct synthesis technique. The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which leads to a shorter and cheaper way to obtain mesoporous carbon, and at the same time incorporate into the framework Zirconium atoms. The material with zirconium oxide (Zr-CMK-3) was successfully synthesized and characterized by X ray diffraction, SEM, RAMAN and textural properties, UV-Vis-DRS, X-ray photoelectron spectroscopy and transmission electron microscopy analyses. Zr-CMK-3 improved significantly the H2 storage behavior (4.6 wt% at 77 K and 10 bar) compared with CMK-3. The synthesized material is promising for hydrogen uptake by means of weak bonding (physisorption). The activity of the samples to the adsorption of hydrogen molecules is attributed to the improved dispersion of the zirconium oxide, as well as the appropriate use of support, which can probably disperse the zirconium on its large surface area, allowing a great dispersion of the zirconium. The Zr+4 cation is an active species to absorb and store hydrogen through a physisorption process and the carbon plays an important role in the dispersion and size of metal particles. A hydrogen storage mechanism on the active surface of the ZrO2 clusters was proposed. First layer of hydrogen molecules can react with the metal cation through a dihydrogen complex (Kubas interaction). The second layer of hydrogen molecules adsorbed around the metal oxide clusters is due to dipole-like interactions, this is because the metal particle induces dipole forces on the hydrogen molecule. The other layers could also interact by dipole forces; however, the interaction force decreases as the distance to the surface increases. The upper layers could interact with the metal cation by dipole-induced bonding; however, the interaction force decreases as the distance to the surface increases.
Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Venosta, Lisandro F.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
Materia
CMK-3
Hydrogen storage
Zirconia
Nivel de accesibilidad
acceso abierto
Condiciones de uso
Attribution-NonCommercial-NoDerivatives 4.0 International
Repositorio
Repositorio Institucional Abierto (UTN)
Institución
Universidad Tecnológica Nacional
OAI Identificador
oai:ria.utn.edu.ar:20.500.12272/15006
Acceder
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network_acronym_str RIAUTN
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network_name_str Repositorio Institucional Abierto (UTN)
spelling Hydrogen storage on a novel nanostructured carbon material modified with zirconiaJuárez , Juliana MaríaVenosta, Lisandro FAnunziata , Oscar AlfredoGómez Costa, Marcos BrunoCMK-3Hydrogen storageZirconiaIn this work, we report the synthesis and characterization of zirconium oxide supported in nanostructured carbon material synthesized by a new direct synthesis technique. The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which leads to a shorter and cheaper way to obtain mesoporous carbon, and at the same time incorporate into the framework Zirconium atoms. The material with zirconium oxide (Zr-CMK-3) was successfully synthesized and characterized by X ray diffraction, SEM, RAMAN and textural properties, UV-Vis-DRS, X-ray photoelectron spectroscopy and transmission electron microscopy analyses. Zr-CMK-3 improved significantly the H2 storage behavior (4.6 wt% at 77 K and 10 bar) compared with CMK-3. The synthesized material is promising for hydrogen uptake by means of weak bonding (physisorption). The activity of the samples to the adsorption of hydrogen molecules is attributed to the improved dispersion of the zirconium oxide, as well as the appropriate use of support, which can probably disperse the zirconium on its large surface area, allowing a great dispersion of the zirconium. The Zr+4 cation is an active species to absorb and store hydrogen through a physisorption process and the carbon plays an important role in the dispersion and size of metal particles. A hydrogen storage mechanism on the active surface of the ZrO2 clusters was proposed. First layer of hydrogen molecules can react with the metal cation through a dihydrogen complex (Kubas interaction). The second layer of hydrogen molecules adsorbed around the metal oxide clusters is due to dipole-like interactions, this is because the metal particle induces dipole forces on the hydrogen molecule. The other layers could also interact by dipole forces; however, the interaction force decreases as the distance to the surface increases. The upper layers could interact with the metal cation by dipole-induced bonding; however, the interaction force decreases as the distance to the surface increases.Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.Fil: Venosta, Lisandro F.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.Peer ReviewedUTN- FRC2026-05-20T20:16:20Z2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articulopdfapplication/pdfapplication/pdfhttps://hdl.handle.net/20.500.12272/15006enginfo:eu-repo/semantics/openAccessAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Juliana María Juárezreponame:Repositorio Institucional Abierto (UTN)instname:Universidad Tecnológica Nacional2026-09-24T12:44:27Zoai:ria.utn.edu.ar:20.500.12272/15006instacron:UTNInstitucionalhttp://ria.utn.edu.ar/Universidad públicaNo correspondehttp://ria.utn.edu.ar/oaigestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:a2026-09-24 12:44:29.076Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacionalfalse
dc.title.none.fl_str_mv Hydrogen storage on a novel nanostructured carbon material modified with zirconia
title Hydrogen storage on a novel nanostructured carbon material modified with zirconia
spellingShingle Hydrogen storage on a novel nanostructured carbon material modified with zirconia
Juárez , Juliana María
CMK-3
Hydrogen storage
Zirconia
title_short Hydrogen storage on a novel nanostructured carbon material modified with zirconia
title_full Hydrogen storage on a novel nanostructured carbon material modified with zirconia
title_fullStr Hydrogen storage on a novel nanostructured carbon material modified with zirconia
title_full_unstemmed Hydrogen storage on a novel nanostructured carbon material modified with zirconia
title_sort Hydrogen storage on a novel nanostructured carbon material modified with zirconia
dc.creator.none.fl_str_mv Juárez , Juliana María
Venosta, Lisandro F
Anunziata , Oscar Alfredo
Gómez Costa, Marcos Bruno
author Juárez , Juliana María
author_facet Juárez , Juliana María
Venosta, Lisandro F
Anunziata , Oscar Alfredo
Gómez Costa, Marcos Bruno
author_role author
author2 Venosta, Lisandro F
Anunziata , Oscar Alfredo
Gómez Costa, Marcos Bruno
author2_role author
author
author
dc.subject.none.fl_str_mv CMK-3
Hydrogen storage
Zirconia
topic CMK-3
Hydrogen storage
Zirconia
dc.description.none.fl_txt_mv In this work, we report the synthesis and characterization of zirconium oxide supported in nanostructured carbon material synthesized by a new direct synthesis technique. The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which leads to a shorter and cheaper way to obtain mesoporous carbon, and at the same time incorporate into the framework Zirconium atoms. The material with zirconium oxide (Zr-CMK-3) was successfully synthesized and characterized by X ray diffraction, SEM, RAMAN and textural properties, UV-Vis-DRS, X-ray photoelectron spectroscopy and transmission electron microscopy analyses. Zr-CMK-3 improved significantly the H2 storage behavior (4.6 wt% at 77 K and 10 bar) compared with CMK-3. The synthesized material is promising for hydrogen uptake by means of weak bonding (physisorption). The activity of the samples to the adsorption of hydrogen molecules is attributed to the improved dispersion of the zirconium oxide, as well as the appropriate use of support, which can probably disperse the zirconium on its large surface area, allowing a great dispersion of the zirconium. The Zr+4 cation is an active species to absorb and store hydrogen through a physisorption process and the carbon plays an important role in the dispersion and size of metal particles. A hydrogen storage mechanism on the active surface of the ZrO2 clusters was proposed. First layer of hydrogen molecules can react with the metal cation through a dihydrogen complex (Kubas interaction). The second layer of hydrogen molecules adsorbed around the metal oxide clusters is due to dipole-like interactions, this is because the metal particle induces dipole forces on the hydrogen molecule. The other layers could also interact by dipole forces; however, the interaction force decreases as the distance to the surface increases. The upper layers could interact with the metal cation by dipole-induced bonding; however, the interaction force decreases as the distance to the surface increases.
Fil: Juárez, Juliana María. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Venosta, Lisandro F.. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Anunziata, Oscar Alfredo. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Fil: Gómez Costa, Marcos Bruno. Universidad Tecnológica Nacional. Facultad Regional Córdoba. Centro de Investigación en Nanociencia y Nanotecnología; Argentina.
Peer Reviewed
description In this work, we report the synthesis and characterization of zirconium oxide supported in nanostructured carbon material synthesized by a new direct synthesis technique. The goal of this new method is to avoid the use of inorganic siliceous template (SBA-15), which leads to a shorter and cheaper way to obtain mesoporous carbon, and at the same time incorporate into the framework Zirconium atoms. The material with zirconium oxide (Zr-CMK-3) was successfully synthesized and characterized by X ray diffraction, SEM, RAMAN and textural properties, UV-Vis-DRS, X-ray photoelectron spectroscopy and transmission electron microscopy analyses. Zr-CMK-3 improved significantly the H2 storage behavior (4.6 wt% at 77 K and 10 bar) compared with CMK-3. The synthesized material is promising for hydrogen uptake by means of weak bonding (physisorption). The activity of the samples to the adsorption of hydrogen molecules is attributed to the improved dispersion of the zirconium oxide, as well as the appropriate use of support, which can probably disperse the zirconium on its large surface area, allowing a great dispersion of the zirconium. The Zr+4 cation is an active species to absorb and store hydrogen through a physisorption process and the carbon plays an important role in the dispersion and size of metal particles. A hydrogen storage mechanism on the active surface of the ZrO2 clusters was proposed. First layer of hydrogen molecules can react with the metal cation through a dihydrogen complex (Kubas interaction). The second layer of hydrogen molecules adsorbed around the metal oxide clusters is due to dipole-like interactions, this is because the metal particle induces dipole forces on the hydrogen molecule. The other layers could also interact by dipole forces; however, the interaction force decreases as the distance to the surface increases. The upper layers could interact with the metal cation by dipole-induced bonding; however, the interaction force decreases as the distance to the surface increases.
publishDate 2021
dc.date.none.fl_str_mv 2021
2026-05-20T20:16:20Z
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.12272/15006
url https://hdl.handle.net/20.500.12272/15006
dc.language.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juliana María Juárez
eu_rights_str_mv openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
Juliana María Juárez
dc.format.none.fl_str_mv pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv UTN- FRC
publisher.none.fl_str_mv UTN- FRC
dc.source.none.fl_str_mv reponame:Repositorio Institucional Abierto (UTN)
instname:Universidad Tecnológica Nacional
reponame_str Repositorio Institucional Abierto (UTN)
collection Repositorio Institucional Abierto (UTN)
instname_str Universidad Tecnológica Nacional
repository.name.fl_str_mv Repositorio Institucional Abierto (UTN) - Universidad Tecnológica Nacional
repository.mail.fl_str_mv gestionria@rec.utn.edu.ar; fsuarez@rec.utn.edu.ar
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